Tian Hui, Tu Teng, Jin Xilian, Li Chenyi, Lin Tao, Dong Qing, Jing Xiaoling, Liu Bo, Liu Ran, Li Da, Liu Zhongkai, Li Quanjun, Peng Hailin, Liu Bingbing
State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China.
School of Science, Shenyang Ligong University, Shenyang 110158, China.
J Am Chem Soc. 2024 Mar 20;146(11):7324-7331. doi: 10.1021/jacs.3c11984. Epub 2024 Mar 6.
The discovery of superconductivity in twisted bilayer graphene has reignited enthusiasm in the field of flat-band superconductivity. However, important challenges remain, such as constructing a flat-band structure and inducing a superconducting state in materials. Here, we successfully achieved superconductivity in BiOSe by pressure-tuning the flat-band electronic structure. Experimental measurements combined with theoretical calculations reveal that the occurrence of pressure-induced superconductivity at 30 GPa is associated with a flat-band electronic structure near the Fermi level. Moreover, in BiOSe, a van Hove singularity is observed at the Fermi level alongside pronounced Fermi surface nesting. These remarkable features play a crucial role in promoting strong electron-phonon interactions, thus potentially enhancing the superconducting properties of the material. These findings demonstrate that pressure offers a potential experimental strategy for precisely tuning the flat band and achieving superconductivity.
扭曲双层石墨烯中超导电性的发现重新点燃了平带超导领域的热情。然而,重要的挑战依然存在,比如在材料中构建平带结构并诱导超导态。在此,我们通过压力调节平带电子结构成功在BiOSe中实现了超导。实验测量与理论计算相结合表明,30吉帕压力诱导的超导现象的出现与费米能级附近的平带电子结构有关。此外,在BiOSe中,在费米能级处观察到一个范霍夫奇点以及明显的费米面嵌套。这些显著特征在促进强电子 - 声子相互作用方面发挥着关键作用,从而有可能增强材料的超导性能。这些发现表明,压力为精确调节平带和实现超导提供了一种潜在的实验策略。