Kim Woochul, Seo Yeonju, Ahn Dante, Kim In Soo, Balamurugan Chandran, Jung Gun Young, Kwon Sooncheol, Kim Hyeonghun, Pak Yusin
Sensor System Research Center, Korea Institute of Science and Technology (KIST), Seoul, 02792, Republic of Korea.
Ceramic Total Solution Center, Korea Institute of Ceramic Engineering and Technology, Icheon, Gyeonggi, 17303, Republic of Korea.
Adv Sci (Weinh). 2024 Jun;11(21):e2308840. doi: 10.1002/advs.202308840. Epub 2024 Mar 9.
Selective spectral discrimination of visible and near-infrared light, which accurately distinguishes different light wavelengths, holds considerable promise in various fields, such as automobiles, defense, and environmental monitoring. However, conventional imaging technologies suffer from various issues, including insufficient spatial optimization, low definition, and optical loss. Herein, a groundbreaking advancement is demonstrated in the form of a dual-band photodiode with distinct near-infrared- and visible-light discrimination obtained via simple voltage control. The approach involves the monolithic stacking integration of methylammonium lead iodide (MAPbI) and Si semiconductors, resulting in a p-Si/n-phenyl-C-butyric acid methyl ester/i-MAPbI/p-spiro-MeOTAD (PNIP) device. Remarkably, the PNIP configuration can independently detect the visible and near-infrared regions without traditional optical filters under a voltage range of 3 to -3 V. In addition, an imaging system for a prototype autonomous vehicle confirms the capability of the device to separate visible and near-infrared light via an electrical bias and practicality of this mechanism. Therefore, this study pushes the boundaries of image sensor development and sets the stage for fabricating compact and power-efficient photonic devices with superior performance and diverse functionality.
对可见光和近红外光的选择性光谱辨别能够精确区分不同的光波长,在汽车、国防和环境监测等各个领域都有着巨大的潜力。然而,传统成像技术存在各种问题,包括空间优化不足、清晰度低和光学损耗。在此,展示了一项突破性进展,即通过简单的电压控制获得具有独特近红外和可见光辨别的双波段光电二极管。该方法涉及甲基碘化铅(MAPbI)和硅半导体的单片堆叠集成,从而形成一个p-Si/n-苯基-C-丁酸甲酯/i-MAPbI/p-螺环-MeOTAD(PNIP)器件。值得注意的是,PNIP结构在3至-3 V的电压范围内无需传统光学滤波器就能独立检测可见光和近红外区域。此外,一款原型自动驾驶车辆的成像系统证实了该器件通过电偏置分离可见光和近红外光的能力以及这种机制的实用性。因此,本研究拓展了图像传感器的发展边界,为制造具有卓越性能和多样功能的紧凑且节能的光子器件奠定了基础。