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碳量子点作为光催化剂对有机染料的降解效率:综述

Degradation Efficiency of Organic Dyes on CQDs As Photocatalysts: A Review.

作者信息

Ikram Zulkifle, Azmat Esha, Perviaz Muhammad

机构信息

Department of Basic and Applied Chemistry, Faculty of Science and Technology, University of Central Punjab, 1- Khayaban-e- Jinnah, Johar Town, Lahore 54000, Pakistan.

出版信息

ACS Omega. 2024 Feb 26;9(9):10017-10029. doi: 10.1021/acsomega.3c09547. eCollection 2024 Mar 5.

Abstract

Across the globe, the task of providing clean and safe drinking water is getting harder. Organic contaminants, including dyes and pharmaceutical medications, are a significant environmental threat, especially in aquatic bodies due to their uncontrolled emission. Therefore, a method for their degradation in water bodies that is both environmentally friendly and commercially feasible must be developed. In the realm of photocatalysis, carbon-based nanomaterials have drawn more attention in the last ten years. Due to their exceptional and distinct qualities, metal-free carbon-based photocatalytic systems have received a lot of attention recently for their ability to degrade organic contaminants into semiconductor quantum dots, which are already available. A class of nanomaterials with a particle size between 2 and 10 nm showing distinct optoelectrical characteristics is among the variety of catalytic quantum dots. This review covers several synthesis techniques such as electrochemical, laser ablation, microwave radiation, hydrothermal, and optical features of CQDs such as the photoluminescent (PL) property and quantum confinement effect. The uses of CQDs in the degradation of various dyes as well as the difficulties that still exist and the opportunities that lie ahead have also been explored.

摘要

在全球范围内,提供清洁安全饮用水的任务正变得愈发艰巨。包括染料和药物在内的有机污染物是重大的环境威胁,尤其是因其无节制排放而对水体造成的威胁。因此,必须开发一种在水体中降解这些污染物的方法,该方法既要环保又要在商业上可行。在光催化领域,碳基纳米材料在过去十年中受到了更多关注。由于其独特的优异特性,无金属碳基光催化系统最近因其能够将有机污染物降解为已有的半导体量子点而备受关注。在各种催化量子点中,有一类粒径在2至10纳米之间、具有独特光电特性的纳米材料。本综述涵盖了几种合成技术,如电化学法、激光烧蚀法、微波辐射法、水热法,以及碳量子点的光学特性,如光致发光(PL)特性和量子限域效应。还探讨了碳量子点在降解各种染料方面的应用,以及仍然存在的困难和未来的机遇。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5f3/10918811/6c5443d9b9ab/ao3c09547_0001.jpg

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