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微波工程制备的NiZrO@GNP作为用于储能应用的高效电极材料。

Microwave engineered NiZrO@GNP as efficient electrode material for energy storage applications.

作者信息

Benitto J John, Vijaya J Judith, Saravanakumar B, Al-Lohedan Hamad, Bellucci Stefano

机构信息

Catalysis and Nanomaterials Research Laboratory, Department of Chemistry, Loyola College Chennai-600034 Tamil Nadu India.

Department of Physics, Dr. Mahalingam College of Engineering and Technology Pollachi Tamil Nadu-642 003 India.

出版信息

RSC Adv. 2024 Mar 11;14(12):8178-8187. doi: 10.1039/d4ra00621f. eCollection 2024 Mar 6.

Abstract

Supercapacitors (SCs) have emerged as attractive energy storage devices due to their rapid charge/discharge rates, long cycle life, and high-power density. However, the development of innovative electrode materials to achieve high-performance remains crucial to meet future requirements in supercapacitor technology. In this work, we have explored the potential of a microwave-engineered NiZrO@GNP composite as a promising electrode material for SCs. A microwave assisted hydrothermal approach was adopted for the fabrication of the NiZrO@GNP nanocomposite. Structural and morphological investigations showed its structural richness and its chemical compositions. When applied as a SC electrode, this innovative combination exhibits battery-like behaviour with higher specific capacity (577.63 C g) with good cyclic stability, and good performance. We have assembled an asymmetric-type two-electrode SC device and analysed its electrochemical features. This NiZrO@GNP device exhibits the specific capacity of 47 C g with capacitance retention of 70% after 2000 charge-discharge cycles. Further research on optimizing the synthesis process and exploring different device configurations could pave the way for even higher-performance supercapacitors in the future.

摘要

超级电容器(SCs)因其快速的充/放电速率、长循环寿命和高功率密度,已成为极具吸引力的储能装置。然而,开发创新的电极材料以实现高性能对于满足超级电容器技术的未来需求仍然至关重要。在这项工作中,我们探索了微波工程化的NiZrO@GNP复合材料作为超级电容器有前景的电极材料的潜力。采用微波辅助水热法制备NiZrO@GNP纳米复合材料。结构和形态研究表明了其结构丰富性和化学成分。当用作超级电容器电极时,这种创新组合表现出类似电池的行为,具有更高的比容量(577.63 C/g)、良好的循环稳定性和优异性能。我们组装了一种非对称型两电极超级电容器装置并分析了其电化学特性。这种NiZrO@GNP装置在2000次充放电循环后比容量为47 C/g,电容保持率为70%。进一步研究优化合成工艺和探索不同的装置配置可为未来更高性能的超级电容器铺平道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6960/10925960/61a080c5dc5f/d4ra00621f-f1.jpg

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