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用于高性能超级电容器电极材料的NF/ZnOx和NF/CoOx纳米结构的简便合成

Facile synthesis of NF/ZnOx and NF/CoOx nanostructures for high performance supercapacitor electrode materials.

作者信息

Kumar Yedluri Anil, Reddy Araveeti Eswar, Bak Jin-Soo, Cho In-Ho, Kim Hee-Je

机构信息

School of Electrical Engineering, Pusan National University Busandaehak-ro 63beon-gil, Geumjeong-gu Busan 46241 Republic of Korea

出版信息

RSC Adv. 2019 Jul 9;9(37):21225-21232. doi: 10.1039/c9ra01809c. eCollection 2019 Jul 5.

Abstract

NF/ZnOx nanocone and NF/CoOx nanoparticle electrode materials were fabricated on a nickel foam surface using a simple chemical bath deposition approach and assessed as an electrode material for high-performance supercapacitors (SCs). The electrochemical properties of the NF/ZnOx and NF/CoOx electrodes were examined by cyclic voltammetry, galvanostatic charge-discharge tests, and electrochemical impedance spectroscopy. The fabricated NF/ZnOx and NF/CoOx SCs devices exhibited a good specific capacitance of 2437 and 2142 F g at a current density of 20 mA g, respectively, in a three electrode system. Furthermore, the NF/ZnOx and NF/CoOx electrode materials showed acceptable long cycle-life stability with 97.8% and 95.8% specific capacitance retention after 3000 cycles at a current density of 22 mA g in a 2 M aqueous KOH solution. Furthermore, the NF/ZnOx and NF/CoOx SCs showed a high energy density of 54.15 W h kg and 47.6 W h kg at a power density of 499.8 W kg and 571.2 W kg, respectively, with maximum operating voltage of 0.5 V. Overall, NF/ZnOx and NF/CoOx electrode materials are promising electrodes for electrochemical energy storage applications.

摘要

采用简单的化学浴沉积方法在泡沫镍表面制备了NF/ZnOx纳米锥和NF/CoOx纳米颗粒电极材料,并将其作为高性能超级电容器(SCs)的电极材料进行评估。通过循环伏安法、恒电流充放电测试和电化学阻抗谱对NF/ZnOx和NF/CoOx电极的电化学性能进行了研究。在三电极体系中,制备的NF/ZnOx和NF/CoOx超级电容器器件在电流密度为20 mA g时,分别表现出2437和2142 F g的良好比电容。此外,在2 M KOH水溶液中,电流密度为22 mA g时,经过3000次循环后,NF/ZnOx和NF/CoOx电极材料的比电容保持率分别为97.8%和95.8%,显示出可接受的长循环寿命稳定性。此外,NF/ZnOx和NF/CoOx超级电容器在功率密度分别为499.8 W kg和571.2 W kg时,能量密度分别为54.15 W h kg和47.6 W h kg,最大工作电压为0.5 V。总体而言,NF/ZnOx和NF/CoOx电极材料是用于电化学储能应用的有前景的电极。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/53db/9066169/f4b9b602b77c/c9ra01809c-f2.jpg

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