• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

Recent advances in the synthesis and applications of fluoranthenes.

作者信息

Türkmen Yunus Emre

机构信息

Department of Chemistry, Faculty of Science, Bilkent University, Ankara 06800, Türkiye.

UNAM - National Nanotechnology Research Center, Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800, Türkiye.

出版信息

Org Biomol Chem. 2024 Apr 3;22(14):2719-2733. doi: 10.1039/d4ob00083h.

DOI:10.1039/d4ob00083h
PMID:38470856
Abstract

As an important subclass of polycyclic aromatic hydrocarbons (PAHs), fluoranthenes continue to attract significant attention in synthetic organic chemistry and materials science. In this article, an overview of recent advances in the synthesis of fluoranthene derivatives along with selected applications is provided. First, methods for fluoranthene synthesis with a classification based on strategic bond disconnections are discussed. Then, the total syntheses of natural products featuring the benzo[]fluoranthene skeleton are covered. Finally, examples of important applications of a variety of fluoranthenes are summarized.

摘要

相似文献

1
Recent advances in the synthesis and applications of fluoranthenes.
Org Biomol Chem. 2024 Apr 3;22(14):2719-2733. doi: 10.1039/d4ob00083h.
2
Total synthesis of the natural product benzo[j]fluoranthene-4,9-diol: an approach to the synthesis of oxygenated benzo[j]fluoranthenes.天然产物苯并[j]荧蒽-4,9-二醇的全合成:含氧苯并[j]荧蒽合成方法。
J Org Chem. 2013 Nov 1;78(21):10860-6. doi: 10.1021/jo401887t. Epub 2013 Oct 11.
3
Aryl hydrocarbon receptor-mediated activity of mutagenic polycyclic aromatic hydrocarbons determined using in vitro reporter gene assay.使用体外报告基因测定法确定诱变多环芳烃的芳烃受体介导活性。
Mutat Res. 2001 Oct 18;497(1-2):49-62. doi: 10.1016/s1383-5718(01)00240-6.
4
Synthesis, Characterization, and Properties of BN-Fluoranthenes.
Org Lett. 2022 Aug 5;24(30):5503-5508. doi: 10.1021/acs.orglett.2c01342. Epub 2022 Jun 22.
5
Occurrence of polycyclic aromatic hydrocarbons in human diet - exposure and risk assessment to consumer health.多环芳烃在人类饮食中的出现——对消费者健康的暴露和风险评估。
Rocz Panstw Zakl Hig. 2021;72(3):253-265. doi: 10.32394/rpzh.2021.0178.
6
[Study on occupational exposure characteristics of Polycyclic Aromatic Hydrocarbons in workers of Carbon Enterprises].[炭素企业工人多环芳烃职业暴露特征研究]
Zhonghua Lao Dong Wei Sheng Zhi Ye Bing Za Zhi. 2019 Aug 20;37(8):635-638. doi: 10.3760/cma.j.issn.1001-9391.2019.08.020.
7
Biotransformation of the high-molecular weight polycyclic aromatic hydrocarbon (PAH) benzo[k]fluoranthene by Sphingobium sp. strain KK22 and identification of new products of non-alternant PAH biodegradation by liquid chromatography electrospray ionization tandem mass spectrometry.由鞘氨醇单胞菌 KK22 对高分子量多环芳烃(PAH)苯并[k]荧蒽的生物转化及液质联用技术对非交替 PAH 生物降解新产物的鉴定。
Microb Biotechnol. 2014 Mar;7(2):114-29. doi: 10.1111/1751-7915.12102. Epub 2013 Dec 11.
8
New Strategies in the Efficient Total Syntheses of Polycyclic Natural Products.多环天然产物高效全合成的新策略。
Acc Chem Res. 2020 Nov 17;53(11):2569-2586. doi: 10.1021/acs.accounts.0c00531. Epub 2020 Nov 2.
9
Persistent oxidation dications from twisted fluoranthenes, benzo[k]fluoranthene and dimethyldibenzo[j.l]fluoranthene: charge delocalization mode, tropicity, and formation of novel 8,8'-bifluoranthenyls. An NMR and theoretical study.扭曲荧蒽、苯并[k]荧蒽和二甲基二苯并[j.l]荧蒽产生的持久性氧化二价阳离子:电荷离域模式、亲合性及新型8,8'-联荧蒽的形成。一项核磁共振和理论研究。
J Org Chem. 2001 Dec 28;66(26):8701-8. doi: 10.1021/jo010571p.
10
Catalytic Enantioselective Synthesis of Axially Chiral Polycyclic Aromatic Hydrocarbons (PAHs) via Regioselective C-C Bond Activation of Biphenylenes.通过联苯的区域选择性 C-C 键活化催化对映选择性合成轴手性多环芳烃 (PAHs)。
J Am Chem Soc. 2020 Mar 11;142(10):4714-4722. doi: 10.1021/jacs.9b12205. Epub 2020 Feb 25.

引用本文的文献

1
Synthesis of acenaphthylene-fused heteroarenes and polyoxygenated benzo[]fluoranthenes via a Pd-catalyzed Suzuki-Miyaura/C-H arylation cascade.通过钯催化的铃木-宫浦/碳氢键芳基化串联反应合成苊烯稠合杂芳烃和多氧化苯并[]荧蒽
Beilstein J Org Chem. 2024 Dec 23;20:3290-3298. doi: 10.3762/bjoc.20.273. eCollection 2024.