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负载生物炭的纳米零价铁活化过硫酸盐降解水中有机污染物的研究进展

Research Progress on the Degradation of Organic Pollutants in Water by Activated Persulfate Using Biochar-Loaded Nano Zero-Valent Iron.

作者信息

Lu Hai, Wang Xiaoyan, Cong Qiao, Chen Xinglin, Li Qingpo, Li Xueqi, Zhong Shuang, Deng Huan, Yan Bojiao

机构信息

Key Laboratory of Songliao Aquatic Environment, Ministry of Education, Jilin Jianzhu University, Changchun 130118, China.

Urban Construction College, Changchun University of Architecture, Changchun 130607, China.

出版信息

Molecules. 2024 Mar 3;29(5):1130. doi: 10.3390/molecules29051130.

Abstract

Biochar (BC) is a new type of carbon material with a high specific surface area, porous structure, and good adsorption capacity, which can effectively adsorb and enrich organic pollutants. Meanwhile, nano zero-valent iron (nZVI) has excellent catalytic activity and can rapidly degrade organic pollutants through reduction and oxidation reactions. The combined utilization of BC and nZVI can not only give full play to their advantages in the adsorption and catalytic degradation of organic pollutants, but also help to reduce the agglomeration of nZVI, thus improving its efficiency in water treatment and providing strong technical support for water resources protection and environmental quality improvement. This article provides a detailed introduction to the preparation method and characterization technology, reaction mechanism, influencing factors, and specific applications of BC and nZVI, and elaborates on the research progress of BC-nZVI in activating persulfate (PS) to degrade organic pollutants in water. It has been proven experimentally that BC-nZVI can effectively remove phenols, dyes, pesticides, and other organic pollutants. Meanwhile, in response to the existing problems in current research, this article proposes future research directions and challenges, and summarizes the application prospects and development trends of BC-nZVI in water treatment. In summary, BC-nZVI-activated PS is an efficient technology for degrading organic pollutants in water, providing an effective solution for protecting water resources and improving environmental quality, and has significant application value.

摘要

生物炭(BC)是一种新型碳材料,具有高比表面积、多孔结构和良好的吸附能力,能够有效吸附和富集有机污染物。同时,纳米零价铁(nZVI)具有优异的催化活性,可通过还原和氧化反应快速降解有机污染物。BC与nZVI的联合利用不仅能充分发挥它们在有机污染物吸附和催化降解方面的优势,还有助于减少nZVI的团聚,从而提高其水处理效率,为水资源保护和环境质量改善提供有力的技术支持。本文详细介绍了BC和nZVI的制备方法与表征技术、反应机理、影响因素及具体应用,并阐述了BC-nZVI活化过硫酸盐(PS)降解水中有机污染物的研究进展。实验证明,BC-nZVI能有效去除酚类、染料、农药等有机污染物。同时,针对当前研究中存在的问题,本文提出了未来的研究方向和挑战,并总结了BC-nZVI在水处理中的应用前景和发展趋势。综上所述,BC-nZVI活化PS是一种高效的水中有机污染物降解技术,为保护水资源和改善环境质量提供了有效的解决方案,具有重要的应用价值。

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