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通过用从炼油废料中获得的回收聚合物和表面活性剂进行改性来提高沥青与矿物填料表面的附着力。

Increasing the Adhesion of Bitumen to the Surface of Mineral Fillers through Modification with a Recycled Polymer and Surfactant Obtained from Oil Refining Waste.

作者信息

Dyuryagina Antonina, Byzova Yuliya, Ostrovnoy Kirill, Demyanenko Alexandr, Lutsenko Aida, Shirina Tatyana

机构信息

Department of Chemistry and Chemical Technology, Manash Kozybayev North Kazakhstan University, Petropavlovsk 150000, Kazakhstan.

出版信息

Polymers (Basel). 2024 Mar 5;16(5):714. doi: 10.3390/polym16050714.

DOI:10.3390/polym16050714
PMID:38475396
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10934658/
Abstract

The purpose of this study was to optimize the processes of wetting fillers by varying the content of such additives as a surfactant and polymer in bitumen-mineral compositions in order to achieve optimal performance. The cosine of the contact angle was used as a criterion for assessing the adhesion of the bitumen binder to the surface of crushed stone. The effect of the additives' concentration on surface tension and adhesive efficiency in binary and ternary bitumen compositions was studied. The following chemicals were used as additives: the original product AS-1, industrial additive AMDOR-10, and used sealant AG-4I, a product based on polyisobutylene and petroleum oils. AS-1 was obtained from the oil refining waste in the laboratory of M. Kozybayev North Kazakhstan University. The ternary "bitumen-AG-4I-AS-1" composition provided a maximum decrease in the contact angle by 15.96° (gray crushed stone) and by 14.06° (red crushed stone) relative to original bitumen, providing better wettability of the mineral filler particles with the bitumen, and as a result, maximum adhesion between the bitumen and crushed stone. The optimal performance of the bitumen-mineral composition was recorded with the joint presence of additives in the bitumen: AS-1 at a level of 1.0 g/dm and AG-4I at a level of 1.0 g/dm.

摘要

本研究的目的是通过改变沥青-矿物组合物中表面活性剂和聚合物等添加剂的含量来优化填料的润湿过程，以实现最佳性能。接触角的余弦值被用作评估沥青粘合剂与碎石表面粘附性的标准。研究了添加剂浓度对二元和三元沥青组合物表面张力和粘附效率的影响。使用以下化学品作为添加剂：原始产品AS-1、工业添加剂AMDOR-10和用过的密封剂AG-4I，一种基于聚异丁烯和石油油的产品。AS-1是在北哈萨克斯坦大学M. Kozybayev实验室从炼油废料中获得的。相对于原始沥青，三元“沥青-AG-4I-AS-1”组合物使接触角最大降低了15.96°（灰色碎石）和14.06°（红色碎石），使矿物填料颗粒与沥青具有更好的润湿性，从而使沥青与碎石之间具有最大的粘附力。当沥青中同时存在添加剂时，记录到沥青-矿物组合物的最佳性能：AS-1的含量为1.0 g/dm，AG-4I的含量为1.0 g/dm。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/fa5f0964bf39/polymers-16-00714-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/137b8d2a53e0/polymers-16-00714-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/51447a3a4548/polymers-16-00714-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/7f4dc55fd128/polymers-16-00714-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/688c1846e48e/polymers-16-00714-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/a2eba554be91/polymers-16-00714-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/2b762ec75375/polymers-16-00714-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/b00a7cab5642/polymers-16-00714-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/fa5f0964bf39/polymers-16-00714-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/137b8d2a53e0/polymers-16-00714-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/467794b643e9/polymers-16-00714-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/d6bbb33f3be2/polymers-16-00714-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/8e3fa9d9ec16/polymers-16-00714-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/3b195fb88375/polymers-16-00714-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/981379a7295b/polymers-16-00714-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/0e231dfe7b23/polymers-16-00714-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/f080aabecb3e/polymers-16-00714-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/51447a3a4548/polymers-16-00714-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/7f4dc55fd128/polymers-16-00714-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/688c1846e48e/polymers-16-00714-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/a2eba554be91/polymers-16-00714-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/2b762ec75375/polymers-16-00714-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/b00a7cab5642/polymers-16-00714-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a882/10934658/fa5f0964bf39/polymers-16-00714-g015.jpg

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