Kabo Gennady J, Blokhin Andrey V, Paulechka Eugene, Roganov Gennady N, Frenkel Michael, Yursha Iosif A, Diky Vladimir, Zaitsau Dzmitry, Bazyleva Ala, Simirsky Vladimir V, Karpushenkava Larisa S, Sevruk Viktor M
Chemistry Department, Belarusian State University, 14 Leningradskaya Street, 220030 Minsk, Belarus.
Thermodynamics Research Center, Applied Chemicals and Materials Division, National Institute of Standards and Technology, 325 Broadway, Boulder, Colorado 80305-3337, USA.
J Chem Thermodyn. 2019 Apr;131. doi: 10.1016/j.jct.2018.10.025.
In this review, results of the studies of thermodynamic properties of organic substances conducted at the Chemistry Department of the Belarusian State University (Minsk, Belarus) over a period of more than 50 years are summarized. Emphasis is made on precise measurements (both calorimetry and equilibria) and prediction methods, including group-contribution, quantum chemical, and statistical mechanical, for a broad range of thermodynamic properties of various classes of chemical substances. The principal purposes of these studies were to establish relationships between thermodynamic properties of organic substances and their molecular structure, develop methods of extrapolation and prediction of the properties of substances lacking experimental data, and provide thermodynamic background for innovative energy- and resource-saving technologies.
在本综述中，总结了白俄罗斯国立大学化学系（白俄罗斯明斯克）在50多年时间里对有机物质热力学性质的研究结果。重点在于对各种化学物质广泛的热力学性质进行精确测量（量热法和平衡法）以及预测方法，包括基团贡献法、量子化学法和统计力学法。这些研究的主要目的是建立有机物质的热力学性质与其分子结构之间的关系，开发对缺乏实验数据的物质性质进行外推和预测的方法，并为创新的节能和资源节约技术提供热力学背景。
