Monomer Dependence of Colorless and Transparent Polyimide Films: Thermomechanical Properties, Optical Transparency, and Solubility.

Six poly(amic acid)s (PAAs) were synthesized by reacting bis(3-aminophenyl) sulfone with various dianhydride monomers such as pyromellitic dianhydride, 4,4'-biphthalic anhydride, dicyclohexyl-3,4,3',4'-tetracarboxylic dianhydride, 4,4'-oxidiphthalic anhydride, 3,3',4,4'-benzophenonetetracarboxylic dianhydride, and 4,4'-(hexafluoroisopropylidene) diphthalic anhydride. These PAAs were then converted to polyimide (PI) films by thermal imidization at various temperatures. To obtain colorless and transparent PI (CPI), the dianhydride monomer used in this study had an overall bent structure, a structure containing a strong electron-withdrawing -CF substituent or an alicyclic ring. In addition, some monomers contained ether or ketone functional groups in their bent structures. The thermomechanical properties, optical transparency, and solubility of CPI films with six different dianhydride monomer structures were investigated, and the correlation between the monomer structure and CPI film properties was clarified. Overall, CPI with an aromatic main chain structure or a linear structure had excellent thermal and mechanical properties. In contrast, CPI with a bent structure containing functional groups or substituents in the main chain exhibited excellent optical transparency and solubility.