光诱导一氧化碳释放分子（光CORM）作为钯催化氨基羰基化反应中一氧化碳的替代物。
Photoinduced CO-releasing molecule (photoCORM) as an CO surrogate for palladium-catalysed aminocarbonylation.
作者信息
Annereau Marcel, Salmain Michèle, Corcé Vincent
机构信息
Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, IPCM, Paris F-75005, France.
出版信息
Chem Commun (Camb). 2024 Apr 4;60(29):3934-3937. doi: 10.1039/d4cc00524d.
PMID:38497545
Abstract
Herein, we show that a photoCORM behaves as a highly substrate-tolerant, photoactivable CO surrogate, allowing the synthesis of variously functionalised amides including the biologically active compound Moclobemide by Pd-catalysed aminocarbonylation between aryl iodides and amines under mild conditions. This work should bring about a useful input to the field of carbonylative transformations.
摘要
在此，我们表明光可活化一氧化碳释放分子（photoCORM）表现为一种高度耐底物、可光活化的一氧化碳替代物，能够在温和条件下通过芳基碘化物与胺之间的钯催化氨羰基化反应合成各种功能化酰胺，包括生物活性化合物吗氯贝胺。这项工作应为羰基化转化领域带来有益的贡献。
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