朝着酰胺的可持续合成迈进：深共熔溶剂中芳基碘的选择性钯催化氨甲酰化反应。
Towards a sustainable synthesis of amides: chemoselective palladium-catalysed aminocarbonylation of aryl iodides in deep eutectic solvents.
机构信息
Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali, Università del Salento, Prov.le Lecce-Monteroni, I-73100, Lecce, Italy.
出版信息
Chem Commun (Camb). 2018 Jul 17;54(58):8100-8103. doi: 10.1039/c8cc03858a.
PMID:29972156
Abstract
A palladium-catalysed aminocarbonylation of (hetero)aryl iodides has, for the first time, been accomplished in deep eutectic solvents as environmentally benign and recyclable media, under mild conditions. The reactions proceeded with a good substrate scope, and a variety of amides have been synthesized in yields up to 98%.
摘要
钯催化（杂）芳基碘代物的氨甲酰化反应首次在深共熔溶剂中完成，该溶剂作为环境友好且可回收的介质，在温和条件下进行。反应具有良好的底物范围，各种酰胺的收率高达 98%。
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