• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

[GeRu(CO)HI]：一种具有芳香环电流的以锗为中心的钌羰基簇合物。

[GeRu(CO)HI]: A Germanium-Centered Ruthenium Carbonyl Cluster with Aromatic Ring Current.

作者信息

Wolf Silke, Köppe Ralf, Treptow Jens, Feuerstein Wolfram, Wenzel Jonas, Breher Frank, Roesky Peter W, Weigend Florian, Klopper Wim, Feldmann Claus

机构信息

Institute for Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131, Karlsruhe, Germany.

Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, D-35043, Marburg, Germany.

出版信息

Adv Sci (Weinh). 2024 Jun;11(21):e2309043. doi: 10.1002/advs.202309043. Epub 2024 Mar 21.

DOI:10.1002/advs.202309043
PMID:38509846
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11151064/
Abstract

The carbonyl cluster compound [GeRu(CO)HI] is unique in regard to its structure and bonding with a GeRu cluster core, a planar GeRuHI unit, extensive multi-center bonding, and an aromatic ring current similar to benzene (9-10 nA T). The open-shell cluster core is a Ge-centered five-membered Ru(Ru) ring with CO ligands and an additional H and I atom, each bridging two Ru atoms on opposite sides of the cluster core. The compound is prepared at 130 °C in a weakly-coordinating ionic liquid.

摘要

羰基簇合物[GeRu(CO)HI]在结构和键合方面独具特色，具有GeRu簇核、平面GeRuHI单元、广泛的多中心键合以及与苯类似的芳香环电流（9 - 10 nA T）。开壳层簇核是以Ge为中心的五元Ru(Ru)环，带有CO配体以及一个额外的H和I原子，每个原子在簇核相对两侧桥连两个Ru原子。该化合物在130°C下于弱配位离子液体中制备而成。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1a/11151064/e1c3a632658a/ADVS-11-2309043-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1a/11151064/6a94f90906f3/ADVS-11-2309043-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1a/11151064/af0e972f4273/ADVS-11-2309043-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1a/11151064/f79abb7af94b/ADVS-11-2309043-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1a/11151064/b1e0383989aa/ADVS-11-2309043-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1a/11151064/e1c3a632658a/ADVS-11-2309043-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1a/11151064/6a94f90906f3/ADVS-11-2309043-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1a/11151064/af0e972f4273/ADVS-11-2309043-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1a/11151064/f79abb7af94b/ADVS-11-2309043-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1a/11151064/b1e0383989aa/ADVS-11-2309043-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1a/11151064/e1c3a632658a/ADVS-11-2309043-g005.jpg

相似文献

1
[GeRu(CO)HI]: A Germanium-Centered Ruthenium Carbonyl Cluster with Aromatic Ring Current.[GeRu(CO)HI]：一种具有芳香环电流的以锗为中心的钌羰基簇合物。
Adv Sci (Weinh). 2024 Jun;11(21):e2309043. doi: 10.1002/advs.202309043. Epub 2024 Mar 21.
2
Ruthenium and osmium carbonyl clusters incorporating stannylene and stannyl ligands.包含亚锡烯和锡烷基配体的钌和锇羰基簇合物。
Dalton Trans. 2008 Aug 28(32):4212-9. doi: 10.1039/b805024d. Epub 2008 Jul 16.
3
IR spectra and structures of saturated ruthenium cluster carbonyl cations Ru(CO) ( = 1-6).饱和钌簇羰基阳离子Ru(CO) （= 1 - 6）的红外光谱和结构
Dalton Trans. 2023 Jul 25;52(29):9929-9939. doi: 10.1039/d3dt01129a.
4
Reactivity Studies on a Binuclear Ruthenium(0) Complex Equipped with a Bridging κ(2)N,Ge-Amidinatogermylene Ligand.配备桥连κ(2)N,Ge-脒基亚锗烯配体的双核钌(0)配合物的反应性研究
Inorg Chem. 2015 May 18;54(10):4850-61. doi: 10.1021/acs.inorgchem.5b00412. Epub 2015 May 6.
5
Multiple additions of phenylgermanium ligands to tetraruthenium and tetraosmium carbonyl cluster complexes.苯基锗配体多次加成到四钌和四锇羰基簇合物上。
Inorg Chem. 2007 Jan 22;46(2):533-40. doi: 10.1021/ic062039w.
6
Nanosized (mu12-Pt)Pd164-xPtx(CO)72(PPh3)20 (x approximately 7) containing Pt-centered four-shell 165-atom Pd-Pt core with unprecedented intershell bridging carbonyl ligands: comparative analysis of icosahedral shell-growth patterns with geometrically related Pd145(CO)x(PEt3)30 (x approximately 60) containing capped three-shell Pd145 core.纳米尺寸的(μ12-Pt)Pd164-xPtx(CO)72(PPh3)20（x约为7），其包含以铂为中心的四壳层165原子钯-铂核以及前所未有的壳间桥连羰基配体：与含有封端三壳层钯145核的几何相关的Pd145(CO)x(PEt3)30（x约为60）的二十面体壳层生长模式的比较分析。
J Am Chem Soc. 2007 Sep 19;129(37):11619-30. doi: 10.1021/ja073945q. Epub 2007 Aug 28.
7
Synthesis of mixed tin-ruthenium and tin-germanium-ruthenium carbonyl clusters from [Ru3(CO)12] and diaminometalenes (M = Sn, Ge).从[Ru3(CO)12]和二胺金属（M = Sn，Ge）合成混合锡-钌和锡-锗-钌羰基簇。
Inorg Chem. 2012 Feb 20;51(4):2569-76. doi: 10.1021/ic202532u. Epub 2012 Jan 11.
8
Ge8R6: the ligands define the bonding situation within the cluster core.Ge8R6：配体决定了簇核内的键合情况。
Dalton Trans. 2005 Oct 21(20):3277-80. doi: 10.1039/b508379f. Epub 2005 Aug 31.
9
Synthesis, characterisation, crystal structures, reactivity, and electrochemistry of ruthenium-nitrido, ruthenium-cobalt-imido and ruthenapyrrolidone carbonyl clusters containing alkyne ligands.含炔烃配体的钌-氮化物、钌-钴-亚胺化物和钌吡咯烷酮羰基簇合物的合成、表征、晶体结构、反应性及电化学性质
Chemistry. 2001 Jan 5;7(1):258-71. doi: 10.1002/1521-3765(20010105)7:1<258::aid-chem258>3.0.co;2-i.
10
Germanium-rich pentaruthenium carbonyl clusters including Ru(5)(CO)(11)(mu-GePh(2))(4)(mu(5)-C) and its reactions with hydrogen.含锗的五钌羰基簇合物，包括Ru(5)(CO)(11)(μ-GePh(2))(4)(μ(5)-C)及其与氢气的反应。
Inorg Chem. 2003 Feb 24;42(4):1328-33. doi: 10.1021/ic020655w.

本文引用的文献

1
Aromaticity: Quo Vadis.芳香性：何去何从。
Chem Sci. 2023 Feb 22;14(21):5569-5576. doi: 10.1039/d2sc04998h. eCollection 2023 May 31.
2
Reactions of noble-metal oxides in ionic liquids near room temperature.室温附近离子液体中贵金属氧化物的反应
RSC Adv. 2023 Apr 11;13(17):11441-11449. doi: 10.1039/d3ra00892d.
3
φ-Aromaticity in prismatic {Bi}-based clusters.棱锥型 {Bi}-基簇中的 φ-芳性。
Nat Chem. 2023 Mar;15(3):347-356. doi: 10.1038/s41557-022-01099-5. Epub 2022 Dec 22.
4
Symmetry collapse due to the presence of multiple local aromaticity in Ge.由于锗中存在多个局部芳香性而导致的对称性崩溃。
Nat Commun. 2022 Apr 20;13(1):2149. doi: 10.1038/s41467-022-29626-5.
5
Integration of global ring currents using the Ampère-Maxwell law.利用安培-麦克斯韦定律整合全球环形电流。
Phys Chem Chem Phys. 2022 Jan 4;24(2):624-628. doi: 10.1039/d1cp05061c.
6
A crystalline tri-thorium cluster with σ-aromatic metal-metal bonding.具有 σ-芳香性金属-金属键的三钍晶体簇。
Nature. 2021 Oct;598(7879):72-75. doi: 10.1038/s41586-021-03888-3. Epub 2021 Aug 23.
7
[BiMo(CO)]: a multiple local σ-aromatic cluster containing a distorted Bi triangular prism.[BiMo(CO)]：一个包含扭曲铋三棱柱的多中心σ-芳香簇合物。
Chem Commun (Camb). 2021 Apr 18;57(30):3656-3659. doi: 10.1039/d1cc00734c. Epub 2021 Mar 16.
8
Substantial π-aromaticity in the anionic heavy-metal cluster [Th@Bi].阴离子重金属团簇[Th@Bi]中存在显著的π芳香性。
Nat Chem. 2021 Feb;13(2):149-155. doi: 10.1038/s41557-020-00592-z. Epub 2020 Dec 7.
9
σ-Aromaticity-Induced Stabilization of Heterometallic Supertetrahedral Clusters [Zn Ge ] and [Cd Ge ].σ-芳香性诱导的异金属超四面体簇[Zn₄Ge₄]和[Cd₄Ge₄]的稳定性
Angew Chem Int Ed Engl. 2020 Sep 21;59(39):17286-17290. doi: 10.1002/anie.202008276. Epub 2020 Aug 13.
10
Electron-Poor Polar Intermetallics: Complex Structures, Novel Clusters, and Intriguing Bonding with Pronounced Electron Delocalization.缺电子极性金属间化合物：复杂结构、新型团簇和具有显著电子离域的有趣成键。
Acc Chem Res. 2018 Jan 16;51(1):49-58. doi: 10.1021/acs.accounts.7b00488. Epub 2017 Dec 18.