Lamba Rohan, Yukta Yukta, Mondal Jiban, Kumar Ram, Pani Balaram, Singh Bholey
School of Chemical Sciences, Indian Institute of Technology Mandi, Mandi, Himachal Pradesh 175075, India.
Department of Chemistry, University of Delhi, Delhi 110007, India.
ACS Appl Bio Mater. 2024 Apr 15;7(4):2086-2127. doi: 10.1021/acsabm.4c00004. Epub 2024 Mar 21.
Carbon nanodots (CNDs), a fascinating carbon-based nanomaterial (typical size 2-10 nm) owing to their superior optical properties, high biocompatibility, and cell penetrability, have tremendous applications in different interdisciplinary fields. Here, in this Review, we first explore the superiority of CNDs over other nanomaterials in the biomedical, optoelectronics, analytical sensing, and photocatalysis domains. Beginning with synthesis, characterization, and purification techniques, we even address fundamental questions surrounding CNDs such as emission origin and excitation-dependent behavior. Then we explore recent advancements in their applications, focusing on biological/biomedical uses like specific organelle bioimaging, drug/gene delivery, biosensing, and photothermal therapy. In optoelectronics, we cover CND-based solar cells, perovskite solar cells, and their role in LEDs and WLEDs. Analytical sensing applications include the detection of metals, hazardous chemicals, and proteins. In catalysis, we examine roles in photocatalysis, CO reduction, water splitting, stereospecific synthesis, and pollutant degradation. With this Review, we intend to further spark interest in CNDs and CND-based composites by highlighting their many benefits across a wide range of applications.
碳纳米点(CNDs)是一种引人入胜的碳基纳米材料(典型尺寸为2-10纳米),因其优异的光学性能、高生物相容性和细胞穿透性,在不同的跨学科领域有着巨大的应用。在此综述中,我们首先探讨碳纳米点在生物医学、光电子学、分析传感和光催化领域相对于其他纳米材料的优势。从合成、表征和纯化技术开始,我们甚至还探讨了围绕碳纳米点的基本问题,如发射起源和激发依赖行为。然后我们探索它们在应用方面的最新进展,重点关注生物/生物医学用途,如特定细胞器生物成像、药物/基因递送、生物传感和光热疗法。在光电子学方面,我们涵盖基于碳纳米点的太阳能电池、钙钛矿太阳能电池,以及它们在发光二极管和白光发光二极管中的作用。分析传感应用包括金属、有害化学物质和蛋白质的检测。在催化方面,我们研究它们在光催化、一氧化碳还原、水分解、立体定向合成和污染物降解中的作用。通过本综述,我们旨在通过强调碳纳米点及其基复合材料在广泛应用中的诸多益处,进一步激发人们对它们的兴趣。