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叶片加工对唑醚·氟酰胺、苯醚甲环唑和茚虫威残留消解的影响:加工因素和消费者安全评估。

Effect of vine leaves processing on Azoxystrobin, Fenazaquin and Indoxacarb residues dissipation: processing factors and consumer safety assessment.

机构信息

Doctoral School of Science and Technology, Platform for Research and Analysis in Environmental Science (EDST-PRASE), Rafik Hariri Campus, Hadath-Baabda, 1003, Lebanon; Laboratoire Interdisciplinaire des Environnements Continentaux, UMR 7360 Université de Lorraine-CNRS, Bd des Aiguillettes, BP 70239, 54506 Vandœuvre-lès-Nancy, France.

Doctoral School of Science and Technology, Platform for Research and Analysis in Environmental Science (EDST-PRASE), Rafik Hariri Campus, Hadath-Baabda, 1003, Lebanon; Department of Plant Protection, Faculty of Agricultural Engineering and Veterinary Medicine, Lebanese University, Dekwaneh-Matn, 90775, Lebanon.

出版信息

Food Chem. 2024 Jul 30;447:139065. doi: 10.1016/j.foodchem.2024.139065. Epub 2024 Mar 19.

DOI:10.1016/j.foodchem.2024.139065
PMID:38513485
Abstract

The effect of vine leaves processing techniques on Azoxystrobin, Fenazaquin, and Indoxacarb residues was investigated. Residue extraction following field application of pesticides and leaf processing was carried out using the QuEChERS method, with analysis conducted by LC-MS/MS. In dry conservation, Azoxystrobin's half-life was estimated to exceed a year, Fenazaquin's was 18 days, and Indoxacarb's was 142 days. Azoxystrobin had a half-life of 261 days, Fenazaquin had a half-life of 9 days, and Indoxacarb's half-life exceeded a year in brine conservation. It is recommended to use dry conservation because it results in an average 60 % reduction in residue levels for the three pesticides. Boiling water significantly reduced pesticide residues (Azoxystrobin -40.3 %, Indoxacarb -22.4 %, and Fenazaquin -28.8 %). It is recommended to use boiling water for washing, as it shows an average removal rate of approximately 30 %. The health risk assessment indicated that consuming vine leaves posed no health risk for consumers, but overall exposure to residues must be considered.

摘要

研究了葡萄叶加工技术对嘧菌酯、苯氧菌胺和茚虫威残留的影响。采用 QuEChERS 方法进行田间施药和叶片加工后的残留提取,采用 LC-MS/MS 进行分析。在干燥保存中,估计嘧菌酯的半衰期超过一年,苯氧菌胺的半衰期为 18 天,茚虫威的半衰期为 142 天。在盐水保存中,嘧菌酯的半衰期为 261 天,苯氧菌胺的半衰期为 9 天,茚虫威的半衰期超过一年。建议使用干燥保存,因为它可使三种农药的残留水平平均降低 60%。沸水显著降低了农药残留(嘧菌酯-40.3%,茚虫威-22.4%,苯氧菌胺-28.8%)。建议使用沸水清洗,因为它的平均去除率约为 30%。健康风险评估表明,食用葡萄叶不会对消费者造成健康风险,但必须考虑整体残留暴露。

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