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通过氧化石墨烯/氧化镍纳米粒子提高天然胶乳的抗菌功效和生物降解性。

Enhancement in antimicrobial efficacy and biodegradation of natural rubber latex through graphene oxide/nickel oxide nanoparticles.

机构信息

Department of Chemistry, Kurukshetra University, Kurukshetra 136119, India.

出版信息

Int J Biol Macromol. 2024 Apr;265(Pt 2):131046. doi: 10.1016/j.ijbiomac.2024.131046. Epub 2024 Mar 20.

DOI:10.1016/j.ijbiomac.2024.131046
PMID:38518945
Abstract

This work aims to fabricate antibacterial natural rubber latex composites by introducing different ratios of graphene oxide (GO) and nickel oxide (NiO) nanoparticles. The nanocomposites were prepared using latex mixing and a two-roll mill process, followed by molding with a heating hydraulic press. Detailed analyses were conducted to evaluate the rheological, chemical, physical, thermal, mechanical, and electrical performance of the composites. Fourier transform infrared spectroscopy (FTIR) was employed to analyze the interaction among different components, while the surface morphology was examined through the field emission scanning electron microscopy (FESEM) technique. The composites with a loading ratio of 1:2 of GO to NiO (optimized concentration) exhibited the highest tensile strength (24.9 MPa) and tear strength (47.4 N/ mm) among all the tested samples. In addition, the composites demonstrated notable antimicrobial activity against Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, and Candida albicans. The thermal stability of the composites was observed up to 315 °C, and their electrical resistivity lies in the insulating range across a temperature span of 25 °C to 50 °C. The research uncovers critical insights into advancing composite materials suitable for diverse applications, featuring inherent antibacterial attributes, robust mechanical properties, resilience to solvent, UV shielding properties, and controlled electrical resistivity capabilities.

摘要

这项工作旨在通过引入不同比例的氧化石墨烯(GO)和氧化镍(NiO)纳米粒子来制备抗菌天然胶乳复合材料。采用胶乳混合和双辊轧机工艺制备纳米复合材料,然后用加热液压机成型。对复合材料的流变、化学、物理、热、机械和电性能进行了详细分析。采用傅里叶变换红外光谱(FTIR)分析不同组分之间的相互作用,用场发射扫描电子显微镜(FESEM)技术观察表面形貌。在所有测试样品中,GO 与 NiO 的负载比为 1:2(最佳浓度)的复合材料表现出最高的拉伸强度(24.9 MPa)和撕裂强度(47.4 N/mm)。此外,复合材料对金黄色葡萄球菌、大肠杆菌、铜绿假单胞菌和白色念珠菌具有显著的抗菌活性。复合材料的热稳定性可观察到 315°C,其电阻率在 25°C 至 50°C 的温度范围内处于绝缘范围。该研究揭示了在推进适用于各种应用的复合材料方面的关键见解,这些复合材料具有内在的抗菌特性、强大的机械性能、耐溶剂性、紫外线屏蔽性能和可控的电阻率能力。

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