Mohd Ghulam, Bhat Irfan Majeed, Kakroo Insha, Balachandran Akshay, Tabasum Ruheena, Majid Kowsar, Wani Mohammad Farooq, Manna Uttam, Ghodake Gajanan, Lone Saifullah
Department of Chemistry, National Institute of Technology (NIT), Jammu & Kashmir 190006, Srinagar, India.
iDREAM (Interdisciplinary Division for Renewable Energy & Advanced Materials, Laboratory for Bioinspired Research on Advanced Interface and Nanomaterials (BRAINS), NIT, Jammu & Kashmir 190006, Srinagar, India.
ACS Omega. 2024 Mar 7;9(11):12725-12733. doi: 10.1021/acsomega.3c08417. eCollection 2024 Mar 19.
Various plant-based materials effectively absorb oil contaminants at the water/air interface. These materials showcase unparalleled efficiency in purging oil contaminants, encompassing rivers, lakes, and boundless oceans, positioning them as integral components of environmental restoration endeavors. In addition, they are biodegradable, readily available, and eco-friendly, thus making them a preferable choice over traditional oil cleaning materials. This study explores the phenomenal properties of the floating Azolla fern (), focusing on its unique hierarchical leaf surface design at both the microscale and nanoscale levels. These intricate structures endow the fern with exceptional characteristics, including superhydrophobicity, high water adhesion, and remarkable oil or organic solvent absorption capabilities. Azolla's leaf surface exhibits a rare combination of dual wettability, where hydrophilic spots on a superhydrophobic base enable the pinning of water droplets, even when positioned upside-down. This extraordinary property, known as the parahydrophobic state, is rare in floating plants, akin to the renowned , setting Azolla apart as a natural wonder. Submerged in water, Azolla leaves excel at absorbing light oils at the air-water interface, demonstrating a notable ability to extract high-density organic solvents. Moreover, Azolla's rapid growth, doubling in the area every 4-5 days, especially in flowing waters, positions it as a sustainable alternative to traditional synthetic oil-cleaning materials with long-term environmental repercussions. This scientific lead could pave the way for more environmentally friendly approaches to mitigate the negative impacts of oil spills and promote a cleaner water ecosystem.
各种植物基材料能有效吸收水/空气界面处的油污。这些材料在清除河流、湖泊及广阔海洋中的油污方面展现出无与伦比的效率,使其成为环境修复工作不可或缺的组成部分。此外,它们可生物降解、易于获取且环保,因此比传统油污清理材料更具优势。本研究探讨了漂浮满江红()的非凡特性,重点关注其在微观和纳米尺度上独特的分层叶片表面设计。这些复杂结构赋予了满江红卓越的特性,包括超疏水性、高水附着力以及出色的油或有机溶剂吸收能力。满江红的叶片表面呈现出罕见的双重润湿性组合,在超疏水基底上的亲水性斑点能使水滴固定,即便叶片倒置。这种非凡特性,即准疏水状态,在漂浮植物中十分罕见,类似于著名的,使满江红成为一种自然奇观。满江红叶片浸没在水中时,在空气 - 水界面处善于吸收轻质油,展现出显著的提取高密度有机溶剂的能力。此外,满江红生长迅速,每4 - 5天面积就会翻倍,尤其是在流动水域中,这使其成为具有长期环境影响的传统合成油污清理材料的可持续替代品。这一科学发现可为更环保的方法铺平道路,以减轻石油泄漏的负面影响并促进更清洁的水生态系统。