• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

不同氧化镁脱硫剂在烟气脱硫中溶解动力学的研究

Investigation into the Dissolution Kinetics of Different MgO Desulfurizers in Flue Gas Desulfurization.

作者信息

Ma Mengyu, Zhao Hongge, Hu Peng

机构信息

School of Chemistry and Pharmaceutical Engineering, Huanghuai University, Zhumadian 463000, P. R. China.

出版信息

ACS Omega. 2024 Mar 7;9(11):12779-12788. doi: 10.1021/acsomega.3c08575. eCollection 2024 Mar 19.

DOI:10.1021/acsomega.3c08575
PMID:38524468
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10956118/
Abstract

The paper introduced hydrophilic functional groups on the surface of the MgO desulfurizer to improve its dispersion and hydrophilicity on the basis of reducing the particle size of the MgO desulfurizer to the nanometer level. Mechanical grinding technology was used to improve the traditional two-step method to lay the foundation for its large-scale production. The stability test showed that the ζ potential of the 5 wt % modified MgO desulfurizer was greater than 50 mV with 30 days of storage, and the sedimentation rate was not more than 7%. The dissolution reactivity and kinetics experiments showed that the decrease of particle size and the increase of hydrophilicity and dispersion were conducive to accelerating the dissolution rate of the MgO desulfurizer and reducing the apparent activation energy. Meanwhile, the good dissolution rate of the modified MgO nanofluids prepared by the improved method could reduce the liquid film mass transfer resistance and prolonged the penetration time.

摘要

该论文在将氧化镁脱硫剂粒径减小至纳米级的基础上，在其表面引入亲水性官能团，以提高其分散性和亲水性。采用机械研磨技术改进传统两步法，为其大规模生产奠定基础。稳定性测试表明，5 wt%改性氧化镁脱硫剂在储存30天时ζ电位大于50 mV，沉降率不超过7%。溶解反应性和动力学实验表明，粒径减小、亲水性和分散性增加有利于加快氧化镁脱硫剂的溶解速率并降低表观活化能。同时，改进方法制备的改性氧化镁纳米流体良好的溶解速率可降低液膜传质阻力并延长渗透时间。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/6c63b51aea68/ao3c08575_0014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/e59e569edcf5/ao3c08575_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/8a252b25e284/ao3c08575_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/d59f7c8c08ab/ao3c08575_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/a76dc3bf4f56/ao3c08575_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/2517390d2a93/ao3c08575_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/21709119cd3f/ao3c08575_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/069a3efc313e/ao3c08575_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/ee52acf4aba4/ao3c08575_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/2e9d206894f2/ao3c08575_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/8b03874b1a6a/ao3c08575_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/608ebf83ad25/ao3c08575_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/d0498facac64/ao3c08575_0012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/5364d7a210d8/ao3c08575_0013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/6c63b51aea68/ao3c08575_0014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/e59e569edcf5/ao3c08575_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/8a252b25e284/ao3c08575_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/d59f7c8c08ab/ao3c08575_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/a76dc3bf4f56/ao3c08575_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/2517390d2a93/ao3c08575_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/21709119cd3f/ao3c08575_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/069a3efc313e/ao3c08575_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/ee52acf4aba4/ao3c08575_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/2e9d206894f2/ao3c08575_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/8b03874b1a6a/ao3c08575_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/608ebf83ad25/ao3c08575_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/d0498facac64/ao3c08575_0012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/5364d7a210d8/ao3c08575_0013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed85/10956118/6c63b51aea68/ao3c08575_0014.jpg

相似文献

1
Investigation into the Dissolution Kinetics of Different MgO Desulfurizers in Flue Gas Desulfurization.不同氧化镁脱硫剂在烟气脱硫中溶解动力学的研究
ACS Omega. 2024 Mar 7;9(11):12779-12788. doi: 10.1021/acsomega.3c08575. eCollection 2024 Mar 19.
2
Effect of relative humidity on the desulfurization performance of calcium-based desulfurizer.相对湿度对钙基脱硫剂脱硫性能的影响。
J Environ Sci (China). 2024 Apr;138:179-188. doi: 10.1016/j.jes.2023.02.057. Epub 2023 Mar 11.
3
Study on the desulfurization performance of calcium-based desulfurizer and NaHCO desulfurizer.研究钙基脱硫剂和 NaHCO 脱硫剂的脱硫性能。
Environ Sci Pollut Res Int. 2023 Feb;30(8):20357-20368. doi: 10.1007/s11356-022-22980-3. Epub 2022 Oct 18.
4
Experiment and Mechanism Analysis of Desulfurization with a MgO-Based Desulfurizer Fixed Bed Method.基于MgO的脱硫剂固定床法脱硫实验与机理分析
ACS Omega. 2020 Nov 17;5(47):30740-30745. doi: 10.1021/acsomega.0c04967. eCollection 2020 Dec 1.
5
Preparation of a new high-performance calcium-based desulfurizer using a steam jet mill.采用蒸汽射流粉碎机制备新型高效钙基脱硫剂。
J Hazard Mater. 2020 May 5;389:121914. doi: 10.1016/j.jhazmat.2019.121914. Epub 2019 Dec 16.
6
Effect of Desulfurization Process Variables on the Properties of Crumb Rubber Modified Asphalt.脱硫工艺变量对橡胶粉改性沥青性能的影响
Polymers (Basel). 2022 Mar 28;14(7):1365. doi: 10.3390/polym14071365.
7
Gas cleaning and hydrogen sulfide removal for COREX coal gas by sorption enhanced catalytic oxidation over recyclable activated carbon desulfurizer.采用可再生活性炭脱硫剂吸附增强催化氧化法净化 COREX 煤气中的气体和去除硫化氢。
Environ Sci Technol. 2014 Feb 18;48(4):2263-72. doi: 10.1021/es4048973. Epub 2014 Feb 4.
8
Recovery of SO and MgO from By-Products of MgO Wet Flue Gas Desulfurization.从氧化镁湿法烟气脱硫副产物中回收氧化硫和氧化镁
Environ Eng Sci. 2014 Nov 1;31(11):621-630. doi: 10.1089/ees.2014.0004.
9
The dissolution kinetics of industrial brine sludge wastes from a chlor-alkali industry as a sorbent for wet flue gas desulfurization (FGD).氯碱工业产生的工业盐水污泥废弃物作为湿法烟气脱硫（FGD）吸附剂的溶解动力学。
J Air Waste Manag Assoc. 2018 Feb;68(2):93-99. doi: 10.1080/10962247.2017.1280097. Epub 2018 Jan 8.
10
Investigation into the Enhancement of Gas-Liquid Mass Transfer of Absorption of HS by MDEA with Carbon Quantum Dots.碳量子点强化MDEA吸收H₂S气液传质的研究
ACS Omega. 2023 Sep 14;8(38):34678-34686. doi: 10.1021/acsomega.3c03597. eCollection 2023 Sep 26.

本文引用的文献

1
The effect of ZIF-67 nanoparticles on the desulfurization performance of deep eutectic solvent based nanofluid system.ZIF-67纳米颗粒对基于深共晶溶剂的纳米流体体系脱硫性能的影响。
J Hazard Mater. 2022 Mar 15;426:128098. doi: 10.1016/j.jhazmat.2021.128098. Epub 2021 Dec 17.
2
Acid-functionalized carbon nanofibers for high stability, thermoelectrical and electrochemical properties of nanofluids.用于提高纳米流体稳定性、热电和电化学性能的酸功能化碳纳米纤维。
J Colloid Interface Sci. 2018 Jun 15;520:50-57. doi: 10.1016/j.jcis.2018.02.042. Epub 2018 Mar 3.
3
Dissolution rate of limestone for wet flue gas desulfurization in the presence of sulfite.
亚硫酸盐存在下用于湿法烟气脱硫的石灰石溶解速率
J Hazard Mater. 2009 Sep 15;168(2-3):1059-64. doi: 10.1016/j.jhazmat.2009.02.156. Epub 2009 Mar 11.