Alfei Silvana, Pandoli Omar Ginoble
Department of Pharmacy (DIFAR), University of Genoa, Viale Cembrano, 4, 16148 Genoa, Italy.
Departamento de Química, Pontifícia Universidade Católica, Rua Marquês de São Vincente, 225, Rio de Janeiro 22451-900, Brazil.
J Xenobiot. 2024 Mar 20;14(1):416-451. doi: 10.3390/jox14010026.
Biochar (BC), also referred to as "black gold", is a carbon heterogeneous material rich in aromatic systems and minerals, preparable by the thermal decomposition of vegetable and animal biomasses in controlled conditions and with clean technology. Due to its adsorption ability and presence of persistent free radicals (PFRs), BC has demonstrated, among other uses, great potential in the removal of environmental organic and inorganic xenobiotics. Bamboo is an evergreen perennial flowering plant characterized by a short five-year growth period, fast harvesting, and large production in many tropical and subtropical countries worldwide, thus representing an attractive, low-cost, eco-friendly, and renewable bioresource for producing BC. Due to their large surface area and increased porosity, the pyrolyzed derivatives of bamboo, including bamboo biochar (BBC) or activated BBC (ABBC), are considered great bio-adsorbent materials for removing heavy metals, as well as organic and inorganic contaminants from wastewater and soil, thus improving plant growth and production yield. Nowadays, the increasing technological applications of BBC and ABBC also include their employment as energy sources, to catalyze chemical reactions, to develop thermoelectrical devices, as 3D solar vapor-generation devices for water desalination, and as efficient photothermal-conversion devices. Anyway, although it has great potential as an alternative biomass to wood to produce BC, thus paving the way for new bio- and circular economy solutions, the study of bamboo-derived biomasses is still in its infancy. In this context, the main scope of this review was to support an increasing production of BBC and ABBC and to stimulate further studies about their possible applications, thus enlarging the current knowledge about these materials and allowing their more rational, safer, and optimized application. To this end, after having provided background concerning BC, its production methods, and its main applications, we have reviewed and discussed the main studies on BBC and ABBC and their applications reported in recent years.
生物炭(BC),也被称为“黑金”,是一种富含芳香体系和矿物质的碳质非均质材料,可通过在可控条件下利用清洁技术对植物和动物生物质进行热分解制备而成。由于其吸附能力以及持久性自由基(PFRs)的存在,生物炭在诸多用途中展现出了在去除环境有机和无机外来化合物方面的巨大潜力。竹子是一种常绿多年生开花植物,其特点是生长周期短,仅五年,收获迅速,并且在全球许多热带和亚热带国家产量巨大,因此是生产生物炭的一种有吸引力、低成本、生态友好且可再生的生物资源。由于竹子的大表面积和增加的孔隙率,竹子的热解衍生物,包括竹生物炭(BBC)或活化竹生物炭(ABBC),被认为是去除废水中和土壤中的重金属以及有机和无机污染物的优良生物吸附材料,从而改善植物生长和产量。如今,BBC和ABBC越来越多的技术应用还包括将它们用作能源、催化化学反应、开发热电器件、作为用于海水淡化的3D太阳能蒸汽发生装置以及高效的光热转换装置。无论如何,尽管竹子作为生产生物炭的替代生物质具有巨大潜力,从而为新的生物和循环经济解决方案铺平了道路,但对竹衍生生物质的研究仍处于起步阶段。在此背景下,本综述的主要目的是支持BBC和ABBC产量的增加,并激发对其可能应用的进一步研究,从而扩大目前对这些材料的认识,并使其应用更加合理、安全和优化。为此,在提供了关于生物炭、其生产方法及其主要应用的背景之后,我们回顾并讨论了近年来关于BBC和ABBC及其应用的主要研究。