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生物炭化过程中轻质芳香烃的释放规律。

Release Pattern of Light Aromatic Hydrocarbons during the Biomass Roasting Process.

机构信息

School of Energy and Power Engineering, Northeast Electric Power University, Jilin 132012, China.

School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300401, China.

出版信息

Molecules. 2024 Mar 7;29(6):1188. doi: 10.3390/molecules29061188.

Abstract

Roasting is an important step in the pretreatment of biomass upgrading. Roasting can improve the fuel quality of biomass, reduce the O/C and H/C ratios in the biomass, and provide the biomass with a fuel quality comparable to that of lignite. Therefore, studying the structure and component evolution laws during biomass roasting treatment is important for the rational and efficient utilization of biomass. When the roasting temperature is 200-300 °C, the cellulose and hemicellulose in the biomass undergo a depolymerization reaction, releasing many monocyclic aromatic hydrocarbons with high reactivity. The proportion of monocyclic aromatic hydrocarbons in biomass roasting products can be effectively regulated by controlling the reaction temperature, residence time, catalyst, baking atmosphere, and other factors in the biomass roasting process. This paper focuses on the dissociation law of organic components in the pretreatment process of biomass roasting.

摘要

烘烤是生物质升级预处理的重要步骤。烘烤可以提高生物质的燃料质量,降低生物质中的 O/C 和 H/C 比,并为生物质提供类似于褐煤的燃料质量。因此,研究生物质烘烤处理过程中的结构和成分演变规律对于生物质的合理高效利用非常重要。当烘烤温度为 200-300°C 时,生物质中的纤维素和半纤维素会发生解聚反应,释放出许多具有高反应性的单环芳烃。通过控制生物质烘烤过程中的反应温度、停留时间、催化剂、烘烤气氛等因素,可以有效地调节生物质烘烤产物中单环芳烃的比例。本文重点研究了生物质烘烤预处理过程中有机成分的分解规律。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c391/10976030/dfe713ced538/molecules-29-01188-g001.jpg

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