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采用多级液膜技术，用溶解于煤油中的磷酸二（2-乙基己基）酯萃取/传输Co2+金属离子。

Extraction/transportation of Co2+ metal ions with bis(2-ethylhexyl) phosphate dissolved in kerosene using a multidropped liquid membrane technique.

作者信息

Demirel Volkan, Donat Ramazan

机构信息

Department of Chemistry, Faculty of Science, Pamukkale University, Denizli, Turkiye.

出版信息

Turk J Chem. 2023 Aug 13;47(6):1355-1369. doi: 10.55730/1300-0527.3619. eCollection 2023.

DOI:10.55730/1300-0527.3619
PMID:38544708
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10965186/
Abstract

The transport properties of Co ions from the aqueous donor phase to aqueous acceptor phase with the recently developed multidroplet liquid membrane (MDLM) extraction system were studied. This system serves as a continuous process for the transportation of ions and requires fewer reagents for starting and conducting the procedure. Moreover, the procedure results in fewer waste chemicals and mixtures in comparison to traditional extraction methods. During extraction, bis(2-ethylhexyl) phosphate (D2EHPA) was used as a carrier material and 5% potassium thiocyanate (KSCN) solution was used to obtain a colored complex for UV-Vis detection. By means of several experiments, the optimum D2EHPA concentration, pH range for both donor and acceptor phases, and temperature range effect on transport kinetics were investigated. In the extraction of cobalt ions with the MDLM system, the activation energy was calculated as = 13.80 kcal mol, and it was found that the extraction was chemically controlled since it was greater than 10 kcal mol.

摘要

利用最近开发的多滴液膜（MDLM）萃取系统，研究了钴离子从水相供体相到水相受体相的传输性质。该系统作为离子传输的连续过程，启动和进行该程序所需的试剂较少。此外，与传统萃取方法相比，该程序产生的废化学品和混合物较少。萃取过程中，使用磷酸二（2-乙基己基）酯（D2EHPA）作为载体材料，并用5%硫氰酸钾（KSCN）溶液获得用于紫外-可见检测的有色络合物。通过多次实验，研究了最佳D2EHPA浓度、供体相和受体相的pH范围以及温度范围对传输动力学的影响。在使用MDLM系统萃取钴离子的过程中，计算出活化能为 = 13.80 kcal mol，并且发现萃取是化学控制的，因为它大于10 kcal mol。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/6d8255bdbadc/tjc-47-06-1355f12.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/71b83658bd4b/tjc-47-06-1355f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/f5faac616a49/tjc-47-06-1355f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/e6141a1a4976/tjc-47-06-1355f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/7a33eeb42daf/tjc-47-06-1355f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/d1608816e2e9/tjc-47-06-1355f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/85e8f4c517e5/tjc-47-06-1355f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/fb5e722eadd8/tjc-47-06-1355f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/6d8255bdbadc/tjc-47-06-1355f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/1999e9c74518/tjc-47-06-1355f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/a6568ebddbfb/tjc-47-06-1355f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/936cef6dd3e3/tjc-47-06-1355f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/61b00aa68456/tjc-47-06-1355f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/71b83658bd4b/tjc-47-06-1355f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/f5faac616a49/tjc-47-06-1355f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/e6141a1a4976/tjc-47-06-1355f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/7a33eeb42daf/tjc-47-06-1355f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/d1608816e2e9/tjc-47-06-1355f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/85e8f4c517e5/tjc-47-06-1355f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/fb5e722eadd8/tjc-47-06-1355f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6367/10965186/6d8255bdbadc/tjc-47-06-1355f12.jpg

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2
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3
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Environ Monit Assess. 2014 Apr;186(4):2589-97. doi: 10.1007/s10661-013-3562-z. Epub 2014 Jan 7.
4
Prediction of extraction efficiency in supported liquid membrane with a stagnant acceptor phase by means of artificial neural network.采用人工神经网络预测停滞接受相支撑液膜中的萃取效率。
J Sep Sci. 2013 Mar;36(5):986-91. doi: 10.1002/jssc.201200105. Epub 2013 Feb 4.
5
Assessment of trace-metal concentrations in Western Reef heron (Egretta gularis) and Siberian gull (Larus heuglini) from southern Iran.评估来自伊朗南部的西部礁鹭（Egretta gularis）和西伯利亚银鸥（Larus heuglini）的痕量金属浓度。
Arch Environ Contam Toxicol. 2012 Aug;63(2):280-7. doi: 10.1007/s00244-012-9762-7. Epub 2012 Apr 6.
6
Determination of metal levels in thirteen fish species from Lakshadweep Sea.测定拉克沙群岛海域 13 种鱼类中的金属含量。
Bull Environ Contam Toxicol. 2012 Jan;88(1):69-73. doi: 10.1007/s00128-011-0459-9. Epub 2011 Nov 5.
7
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8
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9
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