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带有磺酰亚胺连接基的端羟基树枝状大分子作为具有工业重要性的金属的粘结剂。

Hydroxyl-terminated dendrimers with sulfonimide linkers as binders for metals of industrial significance.

作者信息

Abu Sbeih Khaleel, Al Harahsheh Mohammad

机构信息

Department of Chemistry, Faculty of Sciences, Al-Hussein Bin Talal University, Maan, Jordan.

Department of Chemical Engineering, Faculty of Engineering, Jordan University of Science and Technology, Irbid, Jordan.

出版信息

Turk J Chem. 2024 Jan 2;48(1):85-96. doi: 10.55730/1300-0527.3641. eCollection 2024.

Abstract

First- and second-generation hydroxyl-terminated dendrimers were prepared starting from a 1,3-diaminopropane core and sulfonimide linkers. A first-generation mesitylene-derived dendrimer was also prepared with the same terminals. The dendrimers were then reacted with Fe, Al, and UO separately in order to apply the dendrimers for binding these metals, which have important industrial applications and pose environmental problems simultaneously. The prepared dendrimers were also shown to bind Fe selectively from mixtures with Al.

摘要

第一代和第二代羟基封端的树枝状大分子是以1,3 - 二氨基丙烷为核和磺酰亚胺连接体制备的。还制备了具有相同端基的第一代均三甲苯衍生的树枝状大分子。然后将这些树枝状大分子分别与铁、铝和铀酰反应,以便将树枝状大分子用于结合这些金属,这些金属具有重要的工业应用同时也带来环境问题。所制备的树枝状大分子还显示出能从与铝的混合物中选择性地结合铁。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0ffd/10965167/e11e9aa12561/tjc-48-01-0085f1.jpg

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