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ZnFeO@SiO@L-赖氨酸@SOH:制备、表征及其在硫化物氧化和双(吡唑基)甲烷合成中的催化应用

ZnFeO@SiO@L-lysine@SOH: preparation, characterization, and its catalytic applications in the oxidation of sulfides and synthesis of Bis(pyrazolyl)methanes.

作者信息

Ghanbarpour Amir, Ghorbani-Choghamarani Arash, Aghavandi Hamid, Jafari Ahmad

机构信息

Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, 6517838683, Iran.

出版信息

Sci Rep. 2024 Mar 28;14(1):7449. doi: 10.1038/s41598-024-57317-2.

Abstract

Herein, we report the synthesis of ZnFeO@SiO@L-lysine@SOH as a green, novel magnetic nanocatalyst, containing the sulfuric acid catalytic sites on the surface of zinc ferrite as the catalytic support. The physical and chemical properties of raw and modified samples (ZnFeO@SiO@L-lysine@SOH) were characterized by TGA, EDX, PXRD, Map, and FTIR analyses. The prepared nanocatalyst has excellent catalytic activity in synthesizing the oxidation of sulfides to the sulfoxides and Synthesis of pyrazolyl (Bis(pyrazolyl)methane) derivatives under green conditions. This designed nanocatalyst offers several advantages including the use of inexpensive materials and high yield, simple procedure, and commercially available. The synthesized mesoporous nanocatalyst was recovered and reused in five continuous cycles without considerable change in its catalytic activity.

摘要

在此,我们报道了ZnFeO@SiO@L-赖氨酸@SOH作为一种绿色新型磁性纳米催化剂的合成,该催化剂以铁酸锌表面的硫酸催化位点为催化载体。通过热重分析(TGA)、能谱分析(EDX)、粉末X射线衍射(PXRD)、图谱分析和傅里叶变换红外光谱(FTIR)分析对原始样品和改性样品(ZnFeO@SiO@L-赖氨酸@SOH)的物理和化学性质进行了表征。所制备的纳米催化剂在绿色条件下将硫化物氧化为亚砜以及合成吡唑基(双(吡唑基)甲烷)衍生物方面具有优异的催化活性。这种设计的纳米催化剂具有几个优点,包括使用廉价材料、高收率、操作简单且可商购。合成的介孔纳米催化剂经过回收并在五个连续循环中重复使用时,其催化活性没有显著变化。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e223/10978937/75d408a24696/41598_2024_57317_Fig9_HTML.jpg

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