Ye Chen, Zhang De-Shan, Chen Bin, Tung Chen-Ho, Wu Li-Zhu
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, New Cornerstone Laboratory, Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Beijing 100190, P. R. China.
School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, P. R. China.
ACS Cent Sci. 2024 Feb 26;10(3):529-542. doi: 10.1021/acscentsci.3c01561. eCollection 2024 Mar 27.
Photoredox catalytic processes offer the potential for precise chemical reactions using light and materials. The central determinant is identified as interfacial charge transfer, which simultaneously engenders distinctive behavior in the overall reaction. An in-depth elucidation of the main mechanism and highlighting of the complexity of interfacial charge transfer can occur through both diffusive and direct transfer models, revealing its potential for sophisticated design in complex transformations. The fundamental photophysics uncover these comprehensive applications and offer a clue for future development. This research contributes to the growing body of knowledge on interfacial charge transfer in photoredox catalysis and sets the stage for further exploration of this fascinating area of research.
光氧化还原催化过程为利用光和材料进行精确化学反应提供了潜力。核心决定因素被确定为界面电荷转移，这在整体反应中同时产生独特的行为。通过扩散和直接转移模型可以深入阐明主要机制并突出界面电荷转移的复杂性，揭示其在复杂转化中进行精细设计的潜力。基本光物理揭示了这些广泛的应用，并为未来发展提供了线索。这项研究有助于增加关于光氧化还原催化中界面电荷转移的知识体系，并为进一步探索这一迷人的研究领域奠定基础。
