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天然气微波等离子体热解制备可石墨化沥青

Graphitizable Pitch from Microwave Plasma Pyrolysis of Natural Gas.

作者信息

Gharpure Akshay, Viswanathan Vignesh, Mantri Aayush, Skoptsov George, Vander Wal Randy L

机构信息

John and Willie Leone Family Department of Energy and Mineral Engineering and the EMS Energy Institute, Penn State University, University Park, Pennsylvania 16802, United States.

H Quest Vanguard, Inc., 750 William Pitt Way, Pittsburgh, Pennsylvania 15238, United States.

出版信息

ACS Omega. 2024 Mar 13;9(12):14351-14355. doi: 10.1021/acsomega.3c10428. eCollection 2024 Mar 26.

Abstract

An innovative approach of microwave plasma was utilized to convert natural gas into tar, from which a highly graphitizable pitch was derived using fractional distillation. The natural gas-derived pitch (NGDP) was thoroughly characterized, and the graphitizability of the carbonized NGDP was assessed using polarized light microscopy. The NGDP and, for comparison, needle coke, petroleum coke, and shot coke were subjected to graphitization heat treatment (GR) at 2500 °C. Results indicate that the graphitizability of the NGDP exceeds those of all industrial standard cokes. The GR-NGDP showed the highest degree of graphitization and crystallite size among all samples.

摘要

采用一种创新的微波等离子体方法将天然气转化为焦油,通过分馏从中获得高度可石墨化的沥青。对天然气衍生沥青(NGDP)进行了全面表征,并使用偏光显微镜评估了碳化NGDP的可石墨化性。将NGDP以及作为对照的针状焦、石油焦和弹丸焦在2500℃下进行石墨化热处理(GR)。结果表明,NGDP的可石墨化性超过了所有工业标准焦炭。在所有样品中,GR-NGDP表现出最高程度的石墨化和微晶尺寸。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d39d/10975635/78b0319f48ce/ao3c10428_0001.jpg

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