Zhang Xueying, Hou Feng, Du Haiyan, Yan Liwen, Guo Anran, Ma Xiaohui, Liu Jiachen
Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China.
Materials (Basel). 2024 Jan 26;17(3):599. doi: 10.3390/ma17030599.
Ceramic fiber thread is one of the key components in flexible external thermal insulation blankets, and it has been applied in various fields as a flexible ceramic fibrous material with excellent deformability and high-temperature resistance. However, ceramic fiber threads are often subjected to reciprocating friction motion at specific bending angles, making them highly susceptible to abrade and fracture. Enhancing the abrasion resistance performance of ceramic fiber threads under bending conditions is the future trend and remains a significant challenge. Hence, we design and construct a novel polyurethane-modified coating on the ceramic fiber threads to improve their abrasion resistance performance. The effects of the types and concentrations of modifiers on the microstructure, abrasion resistance property, and tensile property of ceramic fiber threads are systematically investigated. The ceramic fiber threads, after modification with hexamethylene diisocyanate waterborne polyurethane (HDI-WPU) with a concentration of 3%, exhibit excellent abrasion resistance properties. The number of friction cycles at fracture of the modified ceramic fiber thread is more than three times, and the tensile strength is more than one and a half times, that of the original ceramic fiber thread, demonstrating the great potential of the HDI-WPU modifier for enhancing the abrasion resistance performance of ceramic fiber threads.
陶瓷纤维线是柔性外部隔热毯的关键部件之一,作为一种具有优异可变形性和耐高温性的柔性陶瓷纤维材料,已在各个领域得到应用。然而,陶瓷纤维线在特定弯曲角度下经常受到往复摩擦运动,使其极易磨损和断裂。提高陶瓷纤维线在弯曲条件下的耐磨性能是未来的发展趋势,并且仍然是一项重大挑战。因此,我们在陶瓷纤维线上设计并构建了一种新型的聚氨酯改性涂层,以提高其耐磨性能。系统研究了改性剂的种类和浓度对陶瓷纤维线的微观结构、耐磨性能和拉伸性能的影响。用浓度为3%的六亚甲基二异氰酸酯水性聚氨酯(HDI-WPU)改性后的陶瓷纤维线表现出优异的耐磨性能。改性陶瓷纤维线断裂时的摩擦循环次数是原始陶瓷纤维线的三倍多,拉伸强度是原始陶瓷纤维线的一倍半以上,这表明HDI-WPU改性剂在提高陶瓷纤维线耐磨性能方面具有巨大潜力。