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用于强化水净化和污染物检测的金属有机框架基材料改性的最新进展。

Recent advancements in modifications of metal-organic frameworks-based materials for enhanced water purification and contaminant detection.

作者信息

Truong Hai Bang, Le Van Nhieu, Zafar Muhammad Nadeem, Rabani Iqra, Do Ha Huu, Nguyen Xuan Cuong, Hoang Bui Vu Khac, Hur Jin

机构信息

Optical Materials Research Group, Science and Technology Advanced Institute, Van Lang University, Ho Chi Minh City, Viet Nam; Faculty of Applied Technology, School of Technology, Van Lang University, Ho Chi Minh City, Viet Nam.

Faculty of Chemical Engineering, Industrial University of Ho Chi Minh City, Ho Chi Minh City, 70000, Viet Nam.

出版信息

Chemosphere. 2024 May;356:141972. doi: 10.1016/j.chemosphere.2024.141972. Epub 2024 Apr 10.

DOI:10.1016/j.chemosphere.2024.141972
PMID:38608780
Abstract

Metal-organic frameworks (MOFs) have emerged as a key focus in water treatment and monitoring due to their unique structural features, including extensive surface area, customizable porosity, reversible adsorption, and high catalytic efficiency. While numerous reviews have discussed MOFs in environmental remediation, this review specifically addresses recent advancements in modifying MOFs to enhance their effectiveness in water purification and monitoring. It underscores their roles as adsorbents, photocatalysts, and in luminescent and electrochemical sensing. Advancements such as pore modification, defect engineering, and functionalization, combined synergistically with advanced materials, have led to the development of recyclable MOF-based nano-adsorbents, Z-scheme photocatalytic systems, nanocomposites, and hybrid materials. These innovations have broadened the spectrum of removable contaminants and improved material recyclability. Additionally, this review delves into the creation of multifunctional MOF materials, the development of robust MOF variants, and the simplification of synthesis methods, marking significant progress in MOF sensor technology. Furthermore, the review addresses current challenges in this field and proposes potential future research directions and practical applications. The growing research interest in MOFs underscores the need for an updated synthesis of knowledge in this area, focusing on both current challenges and future opportunities in water remediation.

摘要

金属有机框架材料(MOFs)因其独特的结构特性,包括高比表面积、可定制的孔隙率、可逆吸附和高催化效率,已成为水处理和监测领域的关键研究热点。尽管已有众多综述讨论了MOFs在环境修复中的应用,但本综述特别关注了MOFs改性方面的最新进展,以提高其在水净化和监测中的有效性。它强调了MOFs作为吸附剂、光催化剂以及在发光和电化学传感方面的作用。诸如孔修饰、缺陷工程和功能化等进展,与先进材料协同作用,推动了可回收的基于MOF的纳米吸附剂、Z型光催化系统、纳米复合材料和杂化材料的发展。这些创新拓宽了可去除污染物的范围,并提高了材料的可回收性。此外,本综述深入探讨了多功能MOF材料的创制、稳健MOF变体的开发以及合成方法的简化,标志着MOF传感器技术取得了重大进展。此外,该综述还讨论了该领域当前面临的挑战,并提出了潜在的未来研究方向和实际应用。对MOFs日益增长的研究兴趣凸显了对该领域知识进行更新整合的必要性,重点关注水修复领域当前的挑战和未来的机遇。

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