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[银川市黄河河漫滩土壤重金属特征、生态风险评价及源解析]

[Characteristics, Ecological Risk Assessment, and Source Apportionment of Soil Heavy Metals in the Yellow River Floodplain of Yinchuan City].

作者信息

Yu Lu-Jia, Ma Hai-Jun, Wang Cui-Ping

机构信息

School of Biological Science and Engineering, North Minzu University, Yinchuan 750021, China.

Ningxia Grape & Wine Innovation Center, Yinchuan 750021, China.

出版信息

Huan Jing Ke Xue. 2024 May 8;45(5):2971-2982. doi: 10.13227/j.hjkx.202305026.

Abstract

In order to study the status and sources of heavy metal pollution in Yinchuan Yellow River floodplain soils, we used inductively coupled plasma mass spectrometry (ICP-MS) to determine the presence of eight heavy metals in 92 soil samples from the Yinchuan Yellow River floodplain and used enrichment factors, geological accumulation index, and potential ecological risk index to analyze and evaluate the characteristics of heavy metal pollution in the study area. Combined correlation analysis, absolute factor analysis-multiple linear regression model (APCS-MLR), positive matrix factorization (PMF), and geostatistics were used to analyze the sources of soil heavy metals. The results showed that the content of eight heavy metals in the surface soil of the Yellow River floodplain in Yinchuan City were lower than the screening value of soil pollution risk in agricultural land; Cu and Pb contents were lower than the background value of Yinchuan City soil, and the contents of the remaining six elements were higher than the background value. The coefficients of variation of Zn and Cd were large and in the medium variation level and were influenced by anthropogenic activities. The heavy metal content varied between different land types and generally showed that wasteland > abandoned farmland > woodland > cultivated land. The average content of Cu and Pb in forest and arable soils was lower than the regional background value, whereas the rest of the heavy metals in different land types were higher than the soil background value. The analysis of enrichment factors showed that Zn and Cd were slightly enriched in the study area, and the cumulative index method and the evaluation of the potential risk of single heavy metals indicated that more than 60% of the sites in the study area were contaminated with Cd at a medium or higher potential ecological hazard. The comprehensive evaluation results of potential ecological risk showed that the overall ecological risk level of the study area was mild. From the distribution of heavy metal ecological risk comprehensive index sample points, only one point was in moderate ecological hazard, and the pollution point showed very few. Comprehensive correlation analysis, APCS-MLR model, PMF model, and geostatistical analysis results confirmed that Zn and Cd in the study area were mainly derived from human activities such as agricultural activities and transportation, and the remaining heavy metals were derived from soil parent materials. The results of this study can provide a scientific basis for the ecological protection and sustainable development of the Yellow River in Yinchuan City.

摘要

为研究银川黄河河漫滩土壤重金属污染状况及来源,采用电感耦合等离子体质谱法(ICP-MS)测定了银川黄河河漫滩92个土壤样品中8种重金属的含量,并运用富集因子、地质累积指数和潜在生态风险指数对研究区重金属污染特征进行分析评价。结合相关性分析、绝对因子分析-多元线性回归模型(APCS-MLR)、正定矩阵因子分解法(PMF)和地统计学方法对土壤重金属来源进行分析。结果表明,银川市黄河河漫滩表层土壤中8种重金属含量均低于农用地土壤污染风险筛选值;Cu、Pb含量低于银川市土壤背景值,其余6种元素含量高于背景值。Zn和Cd变异系数较大,处于中等变异水平,受人为活动影响较大。不同土地利用类型土壤重金属含量存在差异,总体表现为荒地>弃耕地>林地>耕地。林地和耕地土壤中Cu、Pb平均含量低于区域背景值,不同土地利用类型中其余重金属含量均高于土壤背景值。富集因子分析表明,研究区Zn和Cd轻度富集,累积指数法和单因子重金属潜在风险评价表明,研究区60%以上点位Cd存在中等及以上潜在生态危害。潜在生态风险综合评价结果表明,研究区整体生态风险水平为轻度。从重金属生态风险综合指数样点分布来看,仅1个样点处于中等生态危害,污染样点极少。综合相关性分析、APCS-MLR模型、PMF模型和地统计学分析结果证实,研究区Zn和Cd主要来源于农业活动、交通等人类活动,其余重金属来源于土壤母质。本研究结果可为银川市黄河生态保护与可持续发展提供科学依据。

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