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乌龙洞国家森林公园土壤重金属空间分布特征及污染评价

Spatial distribution characteristics and pollution evaluation of soil heavy metals in Wulongdong National Forest Park.

作者信息

Chen Xiaolong, Zhang Hongfeng, Wong Cora Un In

机构信息

Faculty of Humanities and Social Sciences, Macao Polytechnic University, Macao, China.

Department of Management, Henan Institute of Technology, Xinxiang, Henan, China.

出版信息

Sci Rep. 2024 Apr 17;14(1):8880. doi: 10.1038/s41598-024-58259-5.

DOI:10.1038/s41598-024-58259-5
PMID:38632322
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11525477/
Abstract

To scrutinize the spatial distribution attributes of soil heavy metal content and discern its pollution status within the expanse of Wulongdong National Forest Park, a meticulous investigation is imperative. Three altitude gradients of 900, 1000, and 1069 m were selected on the shady and sunny slopes of Wulongdong National Forest Park, and a total of 300 soil sample points were collected. Soil samples were collected in layers, and the contents of seven soil heavy metal elements, Cr, Cd, Hg, Ni, Se, As, and Pb, were measured. With regard to the national soil element background values, the single factor index method, Nemerow index method, and pollution load index were employed to undertake a thorough assessment of soil heavy metal pollution. (1) The contents of heavy metal elements Cr, Se, As, and Pb in the 0-20 cm soil layer of Wulongdong National Forest Park are lower than the national soil element background value and the Henan soil element background value; the Cd and Hg contents exceed the national soil element background value. The value and Henan soil element background value are 2.2 times and 2.92 times the national soil element background value, and 2.75 times and 9.5 times the Henan soil element background value respectively; Ni content is lower than the Henan soil element background value, but higher than the national soil element background value. The background value is 1.03 times its content. The coefficients of variation of the contents of seven heavy metal elements are all greater than 50%, among which Hg shows extreme variation, and the remaining six are highly variable. (2) In the same soil layer, the Cr and As contents are lower on sunny slopes than on shady slopes, and the contents of Pb, Ni, and Hg are generally higher on sunny slopes than on shady slopes. On sunny slopes, the contents of As, Cd, and Hg decrease with increasing altitude, and the Se content increases with increasing altitude; while on shady slopes, the contents of Cr, Se, and As decrease with increasing altitude, and Pb and Hg content increase with the increase of altitude; the content of heavy metal element As increases with the deepening of the soil layer on shady slopes, and the Hg content decreases with the deepening of the soil layer on sunny slopes. The contents of other heavy metal elements have no obvious regularity among different slope directions, altitudes and soil layers. (3) The single factor index evaluation results show that in the 0 ~ 20c soil layer and on the sunny slope, Hg is heavily polluted, Cd is moderately polluted, Ni is lightly polluted, and Cr, Se, As, and Pb are all non-polluted; On the shady slope, Cd and Hg are moderately polluted, and the other five heavy metal elements are in a non-polluting state. (4) The Nemerow index method evaluation results show that in the 0 ~ 20 cm soil layer, the soil on sunny slopes is significantly more polluted by heavy metals than on shady slopes, and the main pollutants are Ni, Cd and Hg. (5) In the 0 ~ 20 cm soil layer of Wulongdong National Forest Park, the three heavy metal elements Ni, Cd and Hg have reached pollution levels, of which Ni is slightly polluted, Cd and Hg are moderately or above polluted; the sunny slope soil is slightly polluted. Heavy metal pollution, no heavy metal pollution on shady slopes.

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b79c/11525477/e477a901cdd3/41598_2024_58259_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b79c/11525477/5f9890f64fc0/41598_2024_58259_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b79c/11525477/428ad29f7f7c/41598_2024_58259_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b79c/11525477/a04d9dcafa6a/41598_2024_58259_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b79c/11525477/e477a901cdd3/41598_2024_58259_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b79c/11525477/5f9890f64fc0/41598_2024_58259_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b79c/11525477/428ad29f7f7c/41598_2024_58259_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b79c/11525477/a04d9dcafa6a/41598_2024_58259_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b79c/11525477/e477a901cdd3/41598_2024_58259_Fig4_HTML.jpg
摘要

为详细考察乌龙洞国家森林公园范围内土壤重金属含量的空间分布特征并识别其污染状况,进行细致调查势在必行。在乌龙洞国家森林公园的阴坡和阳坡选取了900米、1000米和1069米三个海拔梯度,共采集了300个土壤采样点。土壤样本分层采集,并测定了七种土壤重金属元素铬(Cr)、镉(Cd)、汞(Hg)、镍(Ni)、硒(Se)、砷(As)和铅(Pb)的含量。参照国家土壤元素背景值,采用单因子指数法、内梅罗指数法和污染负荷指数对土壤重金属污染进行全面评估。(1)乌龙洞国家森林公园0至20厘米土层中重金属元素铬、硒、砷和铅的含量低于国家土壤元素背景值和河南土壤元素背景值;镉和汞含量超过国家土壤元素背景值。其值和河南土壤元素背景值分别是国家土壤元素背景值的2.2倍和2.92倍,以及河南土壤元素背景值的2.75倍和9.5倍;镍含量低于河南土壤元素背景值,但高于国家土壤元素背景值。其背景值是其含量的1.03倍。七种重金属元素含量的变异系数均大于50%,其中汞呈现极变异性,其余六种为高变异性。(2)在同一土层中,阳坡的铬和砷含量低于阴坡,阳坡的铅、镍和汞含量总体上高于阴坡。在阳坡上,砷、镉和汞的含量随海拔升高而降低,硒含量随海拔升高而增加;而在阴坡上,铬、硒和砷的含量随海拔升高而降低,铅和汞含量随海拔升高而增加;阴坡上重金属元素砷的含量随土层加深而增加,阳坡上汞的含量随土层加深而降低。其他重金属元素的含量在不同坡向、海拔和土层之间无明显规律。(3)单因子指数评价结果表明,在0至20厘米土层及阳坡,汞为重度污染,镉为中度污染,镍为轻度污染,铬、硒、砷和铅均无污染;在阴坡,镉和汞为中度污染,其他五种重金属元素处于无污染状态。(4)内梅罗指数法评价结果表明,在0至20厘米土层中,阳坡土壤受重金属污染程度明显高于阴坡,主要污染物为镍、镉和汞。(5)在乌龙洞国家森林公园0至20厘米土层中,镍、镉和汞三种重金属元素已达到污染水平,其中镍为轻度污染,镉和汞为中度及以上污染;阳坡土壤为轻度污染。阴坡无重金属污染。

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