Botryoidal and spherulitic hematite as experimental evidence of highly acidic conditions in burning coal-waste dumps and potentially on Mars.

In the extreme setting of burning coal-waste dumps in the Upper Silesian Coal Basin in Poland, botryoidal and spherulitic hematite occurs in association with sulphates and chlorides. A series of simple experiments aimed at replicating the conditions leading to the formation of hematite spherules on the burning dumps are described. Goethite synthesised in the laboratory, mixed with various combinations of other reactants, was heated in a heating chamber or a tubular furnace. Temperature, duration of heating, water and oxygen access, and pH were experimental variables. The results show that hematite may form spherules from goethite where access to oxygen is limited and where conditions are strongly acidic. The spherulitic shape of hematite produced due to dynamically changing physicochemical conditions in the burning dumps can be an indicator of an extremely acidic environment during the closing stages of coal-waste self-heating. The conditions of hematitic-spherule formation on burning coal-waste dumps may apply in a variety of other unrelated settings, e.g., waning volcanism, sulphuric acid speleologenesis and even the formation of blueberries on Mars.