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玄武岩纤维和碳酸钙晶须增强煅烧磷石膏的性能评价:个体与混合试验研究

Performance Evaluation of Calcined Phosphogypsum Reinforced with Basalt Fiber and Calcium Carbonate Whiskers: A Study on Individual and Mixed Tests.

作者信息

Jiang Yong, Huo Jichuan, Lei Yonglin, Jia Lujun

机构信息

Basalt Fiber and Composite Key Laboratory of Sichuan Province, Dazhou 635000, China.

School of Materials and Chemistry, Southwest University of Science and Technology, Mianyang 621000, China.

出版信息

Materials (Basel). 2024 Apr 10;17(8):1725. doi: 10.3390/ma17081725.

Abstract

In an effort to appropriately address the insufficient mechanical properties of calcined phosphogypsum, this research intends to explore how to utilize basalt fiber and calcium carbonate whiskers as reinforcing agents. The study delves deep into their impacts on the flexural and compressive strength, toughness, water resistance, and tensile strength of calcined phosphogypsum. In the individual tests, basalt fibers with different lengths (3 mm, 6 mm, 9 mm, and 18 mm) were added at dosages of 0%, 0.5%, 1.0%, and 1.5%, respectively. As clearly demonstrated by the research findings, basalt fiber effectively reinforces the flexural and compressive strength, toughness, and tensile strength of calcined phosphogypsum, though compromising water resistance. Among the various fiber lengths, the 6 mm fibers impose the most advantageous influence on the performance of calcined phosphogypsum. Afterwards, a test was conducted to explore how cross-scale fibers affect the properties of calcined phosphogypsum by mixing 6 mm basalt fibers and calcium carbonate whiskers. As illustrated by the experimental findings, calcium carbonate whisker refines the pores, thereby elevating the flexural strength and toughness of calcined phosphogypsum. Furthermore, it compensates for the water resistance limitations associated with the sole utilization of basalt fiber while further augmenting the tensile strength and strain capacity. Nonetheless, it is particularly noteworthy that heightening the dosage of both calcium carbonate whiskers and basalt fibers concurrently gives rise to augmented porosity of phosphogypsum and lowered compressive strength.

摘要

为了妥善解决煅烧磷石膏力学性能不足的问题,本研究旨在探索如何利用玄武岩纤维和碳酸钙晶须作为增强剂。该研究深入探讨了它们对煅烧磷石膏的抗折强度、抗压强度、韧性、耐水性和抗拉强度的影响。在单独的试验中,分别以0%、0.5%、1.0%和1.5%的剂量添加不同长度(3毫米、6毫米、9毫米和18毫米)的玄武岩纤维。研究结果清楚地表明,玄武岩纤维有效地增强了煅烧磷石膏的抗折强度、抗压强度、韧性和抗拉强度,不过牺牲了耐水性。在各种纤维长度中,6毫米的纤维对煅烧磷石膏的性能产生最有利的影响。之后,通过将6毫米玄武岩纤维和碳酸钙晶须混合进行试验,以探索跨尺度纤维如何影响煅烧磷石膏的性能。实验结果表明,碳酸钙晶须细化了孔隙,从而提高了煅烧磷石膏的抗折强度和韧性。此外,它弥补了仅使用玄武岩纤维时的耐水性限制,同时进一步提高了抗拉强度和应变能力。然而,特别值得注意的是,同时提高碳酸钙晶须和玄武岩纤维的用量会导致磷石膏孔隙率增加和抗压强度降低。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6336/11051318/9f54ddd35fc3/materials-17-01725-g001.jpg

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