Zhang Hongyu, Li Junxia, Fan Wenrui
College of Mechanical and Vehicle Engineering, Taiyuan University of Technology, Taiyuan 030024, China.
Shanxi Province Engineer Technology Research Center for Mine Fluid Control, Taiyuan 030024, China.
Polymers (Basel). 2024 Apr 18;16(8):1143. doi: 10.3390/polym16081143.
The development of high-performance rubber composites has always been a research hotspot in the field of conveyor belt manufacturing. In this work, a rubber cover joint composite made of reduced graphene oxide (rGO) was prepared using latex mixing and mechanical blending methods, with a steel wire rope conveyor belt as the research object, and the influence of the rGO content on the properties of the rubber composite is discussed. The structure and morphology characterization of the rGO/NR rubber show that the addition of rGO does not change its crystal structure, and 1.2 phr rGO is uniformly dispersed throughout the rubber composite. As more rGO is added, the mechanical properties of the rGO rubber cover joint first improve and then worsen. With the addition of 1.2 phr, the cross-linking density increases by 80.6%, the tensile strength of the rubber composites increases by 49.7%, the elongation at break increases by 23.6%, and the adhesion strength increases by 12.4%. The tensile strength of the rGO rubber cover joint can still maintain 72.5% of its pre-thermal aging value. The wear resistance and thermal conductivity increase as more phr is added. When 3.0 phr is added, the wear resistance of the rubber composites increases by 32.9%, the thermal conductivity increases by 118.8%, and the temperature difference at the completion of vulcanization decreases from 4.5 °C to 1.8 °C. The results show that when 1.2 phr of rGO is added, the rubber conveyor belt joint obtains the best comprehensive performance. These enhanced comprehensive properties allow for the practical application of rGO nanomaterials to conveyor belt rubber.
高性能橡胶复合材料的开发一直是输送带制造领域的研究热点。在这项工作中,以钢丝绳输送带为研究对象,采用胶乳混合和机械共混方法制备了一种由还原氧化石墨烯(rGO)制成的橡胶覆盖接头复合材料,并讨论了rGO含量对橡胶复合材料性能的影响。rGO/NR橡胶的结构和形态表征表明,rGO的添加并未改变其晶体结构,且1.2 phr的rGO均匀分散在整个橡胶复合材料中。随着rGO添加量的增加,rGO橡胶覆盖接头的力学性能先提高后恶化。添加1.2 phr时,交联密度提高了80.6%,橡胶复合材料的拉伸强度提高了49.7%,断裂伸长率提高了23.6%,粘合强度提高了12.4%。rGO橡胶覆盖接头的拉伸强度在热老化后仍能保持其热老化前值的72.5%。随着phr添加量的增加,耐磨性和热导率提高。添加3.0 phr时,橡胶复合材料的耐磨性提高了32.9%,热导率提高了118.8%,硫化结束时的温差从4.5℃降至1.8℃。结果表明,添加1.2 phr的rGO时,橡胶输送带接头获得最佳综合性能。这些增强的综合性能使得rGO纳米材料能够实际应用于输送带橡胶。