Guo Huajun, Xia Wenhao, Shan Xiang, Xi Kelai, Peng Bo, Yang Xianzhang, Zou Zhiwen, Yuan Wenfang
Petrochina Hangzhou Research Institute of Geology, Hangzhou 310023, China.
National Key Laboratory of Deep Oil and Gas, China University of Petroleum (East China), Qingdao 266580, China.
ACS Omega. 2024 Apr 11;9(16):18314-18326. doi: 10.1021/acsomega.3c10100. eCollection 2024 Apr 23.
Coal seams of the Yangxia Formation are widespread in the northern part of the Kuqa Depression in the Tarim Basin. During the thermal evolution of the coal seams, the generated fluids of different periods and natures have a significant impact on tight sandstone reservoirs. To further investigate the diagenetic characteristics and reservoir genesis of the tight sandstones due to the influence of coal seams, an in-depth exploration of the causes of dissolution and cementation in the reservoirs was conducted through thin-section casting, cathode luminescence, scanning electron microscopy, carbon-oxygen isotopic analyses, and X-ray diffraction of whole rock and authigenic clay minerals, along with burial evolution history and fluid evolution history. It is suggested that two phases of acidic fluids are mainly produced during the thermal evolution process of coal seams, including an early humic acid and a late organic carboxylic acid. The early phase humic acid plays a purifying role in reservoirs with coarse particles, rigidity-rich particles, and good permeability conditions. It selectively dissolves sedimentary calcareous mud and calcite, and the dissolution products are completely migrated. At the same time, it inhibits early carbonate cementation. The late organic carboxylic acid will dissolve potassium feldspar and some volcanic rock debris, and the dissolution products are difficult to migrate under the sealing conditions caused by lithological differences, which often take the cementation form of siliceous overgrowth and kaolinite or illite. In addition to the cementation resulting from the dissolution products of acidic fluids produced by the coal seams, the CO-rich fluids generated by the coal seam thermal evolution will combine with ions such as Ca from different sources, resulting in two phases of carbonate cementation. Based on the above research, this study summarizes a set of diagenetic evolution models for coal-bearing reservoirs.
阳霞组煤层广泛分布于塔里木盆地库车坳陷北部。在煤层热演化过程中,不同时期、不同性质的生成流体对致密砂岩储层有显著影响。为进一步研究受煤层影响的致密砂岩成岩特征及储层成因,通过薄片铸体、阴极发光、扫描电子显微镜、碳氧同位素分析以及全岩和自生粘土矿物的X射线衍射等方法,结合埋藏演化史和流体演化史,深入探讨了储层中溶解和胶结作用的成因。研究表明,煤层热演化过程中主要产生两个阶段的酸性流体,包括早期腐殖酸和晚期有机羧酸。早期腐殖酸对颗粒较粗、刚性颗粒含量高且渗透率条件好的储层起净化作用。它选择性溶解沉积钙质泥和方解石,溶解产物完全迁移。同时,抑制早期碳酸盐胶结作用。晚期有机羧酸会溶解钾长石和一些火山岩碎屑,在岩性差异导致的封闭条件下,溶解产物难以迁移,常以硅质增生和高岭石或伊利石的胶结形式存在。除了煤层产生的酸性流体溶解产物导致的胶结作用外,煤层热演化产生的富CO流体将与不同来源的Ca等离子结合,导致两期碳酸盐胶结作用。基于上述研究,本研究总结了一套含煤储层的成岩演化模式。