• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Iridium(III)-catalyzed photoredox cross-coupling of alkyl bromides with trialkyl amines: access to α-alkylated aldehydes.

作者信息

Shukla Gaurav, Singh Malkeet, Singh Saurabh, Singh Maya Shankar

机构信息

Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi-211005, India.

出版信息

Chem Commun (Camb). 2024 May 16;60(41):5435-5438. doi: 10.1039/d4cc01043d.

DOI:10.1039/d4cc01043d
PMID:38686503
Abstract

A C(sp)-C(sp) cross coupling approach based on an iridium-photocatalytic radical process has been developed enabling the synthesis of various α-alkylated aldehydes from easily available/synthesized alkyl bromides and trialkyl amines under mild photocatalytic conditions. The synthesized aldehydes are also explored as a functional handle for various useful products such as carboxylic acid, alcohol and N-heterocycle synthesis.

摘要

相似文献

1
Iridium(III)-catalyzed photoredox cross-coupling of alkyl bromides with trialkyl amines: access to α-alkylated aldehydes.
Chem Commun (Camb). 2024 May 16;60(41):5435-5438. doi: 10.1039/d4cc01043d.
2
Ni/Photoredox-Catalyzed C(sp)-C(sp) Cross-Coupling of Alkyl Pinacolboronates and (Hetero)Aryl Bromides.镍/光氧化还原催化的频哪醇硼酸烷基酯与（杂）芳基溴的C(sp)-C(sp)交叉偶联反应
Org Lett. 2022 Aug 12;24(31):5663-5668. doi: 10.1021/acs.orglett.2c01942. Epub 2022 Aug 3.
3
Cross-Coupling of Alkyl Redox-Active Esters with Benzophenone Imines: Tandem Photoredox and Copper Catalysis.烷基氧化还原活性酯与二苯甲酮亚胺的交叉偶联：串联光氧化还原和铜催化。
Angew Chem Int Ed Engl. 2018 Jul 20;57(30):9501-9504. doi: 10.1002/anie.201804873. Epub 2018 Jun 28.
4
Copper-Catalyzed Enantioconvergent Cross-Coupling of Racemic Alkyl Bromides with Azole C(sp )-H Bonds.铜催化外消旋烷基溴化物与唑 C(sp )-H 键的对映转化交叉偶联反应。
Angew Chem Int Ed Engl. 2021 Jan 4;60(1):380-384. doi: 10.1002/anie.202009527. Epub 2020 Oct 28.
5
Photoinduced C(sp)-H Functionalization of Glycine Derivatives: Preparation of Unnatural α-Amino Acids and Late-Stage Modification of Peptides.甘氨酸衍生物的光诱导C(sp)-H官能团化：非天然α-氨基酸的制备及肽的后期修饰
Acc Chem Res. 2023 Aug 1;56(15):2110-2125. doi: 10.1021/acs.accounts.3c00260. Epub 2023 Jul 19.
6
Synthesis of -Alkyl Glycosides from Alkyl Bromides and Glycosyl Carboxylic Acids via Ni/Photoredox Dual Catalysis.通过镍/光氧化还原双催化由烷基溴化物和糖基羧酸合成α-烷基糖苷
J Org Chem. 2024 Aug 16;89(16):11136-11147. doi: 10.1021/acs.joc.4c00533. Epub 2024 Aug 6.
7
Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross-Coupling of Primary Aryl Amines with Aryl Halides.高化学选择性铱光氧化还原和镍催化的芳基伯胺与芳基卤化物的交叉偶联反应。
Angew Chem Int Ed Engl. 2016 Oct 10;55(42):13219-13223. doi: 10.1002/anie.201604429.
8
Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development.光氧化还原介导的自由基生成途径：催化自由基生成在合成方法开发中的价值。
ACS Catal. 2017 Apr 7;7(4):2563-2575. doi: 10.1021/acscatal.7b00094. Epub 2017 Mar 14.
9
Ketones from aldehydes via alkyl C(sp)-H functionalization under photoredox cooperative NHC/palladium catalysis.通过光氧化还原协同 NHC/钯催化，从醛到酮的烷基 C(sp)-H 功能化。
Nat Commun. 2023 Jul 8;14(1):4044. doi: 10.1038/s41467-023-39707-8.
10
Mechanistic Study on the Decarboxylative C-N Cross-Coupling between Alkyl Carboxylic Acids and Nitrogen Nucleophiles via Dual Copper and Photoredox Catalysis.双铜和光氧化还原催化下通过羧酸烷基和氮亲核试剂的脱羧 C-N 交叉偶联反应的机理研究。
Inorg Chem. 2019 Oct 7;58(19):12669-12677. doi: 10.1021/acs.inorgchem.9b01477. Epub 2019 Sep 9.