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PVA 和马黛茶提取物对羧甲基木薯淀粉/PVA 共混物挤出薄膜的影响:用于抗氧化和机械抗性食品包装。

Effects of PVA and yerba mate extract on extruded films of carboxymethyl cassava starch/PVA blends for antioxidant and mechanically resistant food packaging.

机构信息

Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Física, Laboratorio de Polímeros y Materiales Compuestos, Buenos Aires, Argentina.

Instituto de Ingenierías y Nuevas Tecnologías, Universidad Nacional del Oeste, San Antonio de Padua, Buenos Aires, Argentina; CONICET, Buenos Aires, Argentina.

出版信息

Int J Biol Macromol. 2024 May;268(Pt 1):131464. doi: 10.1016/j.ijbiomac.2024.131464. Epub 2024 May 3.

Abstract

Global concerns over environmental damage caused by non-biodegradable single-use packaging have sparked interest in developing biomaterials. The food packaging industry is a major contributor to non-degradable plastic waste. This study investigates the impact of incorporating different concentrations of polyvinyl alcohol (PVA) and yerba mate extract as a natural antioxidant into carboxymethyl cassava starch films to possibly use as active degradable packaging to enhance food shelf life. Films with starch and PVA blends (SP) at different ratios (SP radios of 100:0, 90:10, 80:20 and 70:30) with and without yerba mate extract (Y) were successfully produced through extrusion and thermoforming. The incorporation of up to 20 wt% PVA improved starch extrusion processing and enhanced film transparency. PVA played a crucial role in improving the hydrophobicity, tensile strength and flexibility of the starch films but led to a slight deceleration in their degradation in compost. In contrast, yerba mate extract contributed to better compost degradation of the blend films. Additionally, it provided antioxidant activity, particularly in hydrophilic and lipophilic food simulants, suggesting its potential to extend the shelf life of food products. Starch-PVA blend films with yerba mate extract emerged as a promising alternative for mechanically resistant and active food packaging.

摘要

全球对不可生物降解的一次性包装造成的环境破坏的担忧,引发了人们对生物材料开发的兴趣。食品包装行业是不可降解塑料废物的主要来源之一。本研究探讨了在羧甲基木薯淀粉薄膜中加入不同浓度的聚乙烯醇(PVA)和马黛茶提取物作为天然抗氧化剂的影响,以期将其用作具有活性的可降解包装,以延长食品的保质期。通过挤出和热成型成功制备了淀粉与 PVA 不同比例(SP 比值为 100:0、90:10、80:20 和 70:30)的混合薄膜(SP)和添加或不添加马黛茶提取物(Y)的薄膜。添加高达 20wt%的 PVA 可改善淀粉挤出加工性能并提高薄膜的透明度。PVA 在提高淀粉薄膜的疏水性、拉伸强度和柔韧性方面发挥了关键作用,但在堆肥中的降解速度略有减慢。相比之下,马黛茶提取物有助于提高共混薄膜的堆肥降解性能。此外,它还提供了抗氧化活性,特别是在亲水和亲脂性食品模拟物中,这表明它有可能延长食品的保质期。含有马黛茶提取物的淀粉-PVA 共混薄膜作为一种有前途的机械抗性和活性食品包装材料脱颖而出。

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