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尼日利亚尼日尔三角洲城市环境土壤和灰尘中的有机氯农药污染。

Organochlorine pesticide contamination of soils and dust from an urban environment in the Niger Delta of Nigeria.

机构信息

Department of Chemistry, Delta State University, P.M.B. 1, Abraka, Nigeria.

Department of Chemistry, Delta State University, P.M.B. 1, Abraka, Nigeria.

出版信息

Sci Total Environ. 2024 Aug 15;938:172959. doi: 10.1016/j.scitotenv.2024.172959. Epub 2024 May 3.

Abstract

The concentrations, sources, and risk of twenty organochlorine pesticides (OCPs) in soils and dusts from a typical urban setting in the Niger Delta of Nigeria were examined. The Σ20 OCP concentrations (ng g) varied from 4.49 to 150 with an average value of 32.6 for soil, 4.67 to 21.5 with an average of 11.7 for indoor dust, and 1.6 to 96.7 with an average value of 23.5 for outdoor dust. The Σ20 OCP concentrations in these media were in the order: soil > outdoor dust > indoor dust, which was in contrast with the order of the detection frequency, i.e., indoor dust (95 to 100 %) > soil (60 to 90 %) > outdoor dust (30 to 80 %). The concentrations of the different OCP classes in these media followed the order: aldrin + dieldrin + endrin and its isomers (Drins) > chlordanes > dichlorodiphenyltrichloroethane (DDTs) > hexachlorocyclohexane (HCHs) > endosulfans for outdoor dust and soil, while that of the indoor dust followed the order: Drins > chlordanes > endosulfans > DDTs > HCHs. The cancer risk values for human exposure to OCPs in these sites exceeded 10 which indicates possible carcinogenic risks. The sources of OCPs in these media reflected both past use and recent inputs.

摘要

本研究调查了尼日利亚尼日尔三角洲典型城区土壤和灰尘中二十种有机氯农药(OCPs)的浓度、来源和风险。Σ20 OCP 浓度(ng/g)范围为 4.49 至 150,平均值为 32.6,土壤中为 4.67 至 21.5,平均值为 11.7,室内灰尘中为 1.6 至 96.7,平均值为 23.5,室外灰尘中为 23.5。这些介质中的Σ20 OCP 浓度顺序为:土壤>室外灰尘>室内灰尘,与检测频率顺序相反,即室内灰尘(95%至 100%)>土壤(60%至 90%)>室外灰尘(30%至 80%)。这些介质中不同 OCP 类别的浓度顺序为:艾氏剂+狄氏剂+异狄氏剂(Drins)>氯丹>滴滴涕(DDTs)>六氯环己烷(HCHs)>硫丹,室外灰尘和土壤中为艾氏剂+狄氏剂+异狄氏剂(Drins)>氯丹>硫丹>滴滴涕(DDTs)>六氯环己烷(HCHs),而室内灰尘中则为 Drins>氯丹>硫丹>DDTs>HCHs。这些地点人类接触 OCPs 的癌症风险值超过 10,表明可能存在致癌风险。这些介质中 OCPs 的来源反映了过去的使用和最近的输入。

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