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作为一种新型的低成本水处理吸附剂:对结晶紫具有高效吸附作用。

as a new low-cost adsorbent for water treatment: highly effective adsorption of crystal violet.

机构信息

Department of Chemistry, University Ibn Zohr, Agadir, Morocco.

Laboratory of Chemical Engineering and Valorization of Resources, Abdelmalek Essaadi University, Tangier, Morocco.

出版信息

Int J Phytoremediation. 2024;26(10):1691-1700. doi: 10.1080/15226514.2024.2349703. Epub 2024 May 9.

DOI:10.1080/15226514.2024.2349703
PMID:38725313
Abstract

Synthetic dyes are prevalent in aquatic environments, they have high toxicities, are non-degradable, and accumulate in the water. The removal of Crystal violet (CV) is carried out using batch experiments on the Salsola Tetragona (ST) plant as a novel adsorbent. The prepared adsorbent was analyzed by various methods (MEB, EDX, IRTF and PZC), to support its applicability as adsorbent. The adsorption study of CV is performed by optimizing the parameters affecting the adsorption process. The adsorption kinetics study is represented by pseudo-second-order (R = 0.999) and the adsorption process is limited by external mass transport. In addition, the isotherm results demonstrate that the Langmuir model interprets better the adsorption isotherm. The thermodynamic parameters suggest that the adsorption phenomena are spontaneous and exothermic. Furthermore, the adsorption reactions involved are of physisorption type, which facilitates the desorption of pollutants from the surface of the adsorbent. The results show that ST adsorbent effectively removes CV in an aqueous solution, which is demonstrated by the maximum amount adsorption of 246.7 mg.g at optimum adsorption conditions: pH = 6, adsorbent dose of 0.5 g.L, initial CV concentration of 10 mg.L, and adsorption time of 30 min at 298 K. Finally, these results can be considered as a useful reference for wastewater treatment using ST.

摘要

合成染料普遍存在于水生环境中,它们具有高毒性、不可降解性,并在水中积累。使用四翅滨藜(ST)植物作为新型吸附剂,通过批量实验去除结晶紫(CV)。通过各种方法(MEB、EDX、IRT 和 PZC)分析制备的吸附剂,以支持其作为吸附剂的适用性。通过优化影响吸附过程的参数来进行 CV 的吸附研究。吸附动力学研究由伪二阶(R = 0.999)表示,吸附过程受外部质量传递限制。此外,等温线结果表明,Langmuir 模型更好地解释了吸附等温线。热力学参数表明吸附现象是自发和放热的。此外,吸附反应是物理吸附类型,有利于污染物从吸附剂表面解吸。结果表明,ST 吸附剂在水溶液中有效地去除 CV,在最佳吸附条件下,吸附量最大为 246.7 mg.g:pH = 6,吸附剂用量 0.5 g.L,初始 CV 浓度为 10 mg.L,在 298 K 下吸附 30 分钟。最后,这些结果可被视为使用 ST 处理废水的有用参考。

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