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合成双子离子液体作为石油领域中碳钢缓蚀剂的电化学及表面研究。

An electrochemical, and surface studies of synthesized Gemini ionic liquid as corrosion inhibitor for carbon steel in petroleum field.

作者信息

Selim Yousef A, Abd-El-Raouf M, Zakaria K, Sayed Ahmed Z, Moustafa Yasser M, Ashmawy Ashraf M

机构信息

Chemistry Department, Faculty of Science, Al-Azhar University, Nasr City, 11884, Cairo, Egypt.

Egyptian Petroleum Research Institute (EPRI), Nasr City, P.O. 11727, Cairo, Egypt.

出版信息

Sci Rep. 2024 May 10;14(1):10766. doi: 10.1038/s41598-024-58321-2.

Abstract

In this work, we study the efficiency of N, N-dibenzyl-N, N, N, N-tetramethylpropane-1,3-diaminium chloride, as anticorrosion. This compound exhibits potential as a prospective remedy to stop the deterioration of carbon steel caused by corrosion in 1.0 M HCl. The synthesis of this compound is described in a comprehensive manner, and its composition is supported by a range of precise analytical approaches such as elemental analysis, and mass spectroscopy. Based on the findings of the investigation, the synthesized Gemini ionic liquid demonstrates a robust capacity to slow down the rate at which the metal corrodes. The Prepared compound was evaluation by electrochemical and morphology study. Our results revealed that elevating the inhibitor concentration led to an augmentation in inhibition effectiveness, reaching up to 94.8% at 200 ppm of the synthesized compound at 298 K. It is crucial to emphasize that the recently prepared Gemini ionic liquid is consistent with the Langmuir adsorption model and function as a mixed inhibitor, participating in the physio-chemisorption process of adsorption.

摘要

在这项工作中,我们研究了N,N - 二苄基 - N,N,N,N - 四甲基丙烷 - 1,3 - 二氯化铵作为防腐剂的效率。该化合物展现出作为一种潜在补救措施的潜力,以阻止碳钢在1.0 M盐酸中因腐蚀而劣化。对该化合物的合成进行了全面描述,并且其组成通过一系列精确的分析方法得到支持,如元素分析和质谱分析。基于研究结果,合成的双子离子液体显示出强大的减缓金属腐蚀速率的能力。通过电化学和形态学研究对制备的化合物进行了评估。我们的结果表明,提高抑制剂浓度会导致抑制效果增强,在298 K下,合成化合物浓度为200 ppm时抑制效率高达94.8%。必须强调的是,新制备的双子离子液体符合朗缪尔吸附模型,并作为一种混合抑制剂发挥作用,参与吸附的物理化学吸附过程。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d4b/11087565/729e4c7f4b45/41598_2024_58321_Fig1_HTML.jpg

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