Rudawska Anna, Frigione Mariaenrica, Sarcinella Antonella, Brunella Valentina, Di Lorenzo Ludovica, Olewnik-Kruszkowska Ewa
Faculty of Mechanical Engineering, Lublin University of Technology, Nadbystrzycka 36, 20-618 Lublin, Poland.
Department of Innovation Engineering, University of Salento, Via Arnesano, 73100 Lecce, Italy.
Materials (Basel). 2024 Apr 29;17(9):2092. doi: 10.3390/ma17092092.
This research study focused on the effect of adding boric acid to epoxy resin in order to obtain a composite material with improved properties and performance. To this end, a fine powder of boric acid (HBO) was introduced into epoxy resin in different amounts, i.e., 0.5 g, 1.0 g, and 1.5 g. As the matrix of the epoxy composites, styrene-modified epoxy resin based on bisphenol A (BPA) (Epidian 53) was used. It was cross-linked with two types of curing agents, i.e., an amine (ET) and a polyamide (PAC). The mechanical properties of the obtained epoxy composites (in terms of compressive strength, compressive modulus, and compressive strain) were determined at room temperature in order to assess the effect of the addition of boron acid and of the type of curing agent employed to cure the epoxy on these characteristics. Calorimetric measurements were made to highlight any changes in the glass transition temperature (Tg) as a result of the addition of boric acid to epoxy resin. Finally, flammability tests were performed on both Epidian 53/PAC and Epidian 53/ET epoxy composites to analyze their fire behavior and consequently establish the effectiveness of the selected additive as a flame retardant.
本研究聚焦于向环氧树脂中添加硼酸以获得性能得到改善的复合材料。为此,将不同量(即0.5克、1.0克和1.5克)的硼酸细粉(HBO)引入环氧树脂中。作为环氧复合材料的基体,使用了基于双酚A(BPA)的苯乙烯改性环氧树脂(Epidian 53)。它与两种固化剂交联,即胺(ET)和聚酰胺(PAC)。在室温下测定所得环氧复合材料的力学性能(以抗压强度、压缩模量和压缩应变表示),以评估添加硼酸和用于固化环氧树脂的固化剂类型对这些特性的影响。进行量热测量以突出由于向环氧树脂中添加硼酸而导致的玻璃化转变温度(Tg)的任何变化。最后,对Epidian 53/PAC和Epidian 53/ET环氧复合材料进行燃烧性测试,以分析它们的燃烧行为,从而确定所选添加剂作为阻燃剂的有效性。