基于三角形羧酸盐核{Fe(μ-O)(μ-OCR)}和脂肪族二胺的配位聚合物
Coordination Polymer Based on a Triangular Carboxylate Core {Fe(μ-O)(μ-OCR)} and an Aliphatic Diamine.
作者信息
Bushuev Vladimir A, Gogoleva Natalia V, Nikolaevskii Stanislav A, Novichihin Sergey V, Yambulatov Dmitriy S, Kiskin Mikhail A, Eremenko Igor L
机构信息
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Prosp., 119991 Moscow, Russia.
Higher School of Economics, National Research University, 101000 Moscow, Russia.
出版信息
Molecules. 2024 May 3;29(9):2125. doi: 10.3390/molecules29092125.
Interaction of the pre-organized complex of iron(II) trimethylacetate and 1,10-phenanthroline (phen) [Fe(piv)(phen)] () (piv = (Me)CCO)) with 1,6-diaminohexane (dahx) in anhydrous acetonitrile yielded a 1D coordination polymer [FeO(piv)(dahx)] () and an organic salt of pivalic acid (Hdahx)(piv) (). The structure of the obtained compounds was determined by single-crystal X-ray diffraction analysis. The phase purity of the complexes was determined by powder X-ray diffraction analysis. According to the single-crystal X-ray analysis, coordination polymer is formed due to the binding of a triangular carboxylate core {Fe(μ-O)(μ-piv)} with an aliphatic diamine ligand. Thermal behavior was investigated for compounds and in an argon atmosphere.
在无水乙腈中，三甲基乙酸亚铁（II）与1,10 - 菲咯啉（phen）形成的预组装配合物[Fe(piv)(phen)]（piv = (Me)CCO））与1,6 - 二氨基己烷（dahx）相互作用，生成了一维配位聚合物[FeO(piv)(dahx)]以及新戊酸的有机盐（Hdahx）(piv)。通过单晶X射线衍射分析确定了所得化合物的结构。通过粉末X射线衍射分析确定了配合物的相纯度。根据单晶X射线分析，配位聚合物是由于三角形羧酸根基核{Fe(μ - O)(μ - piv)}与脂肪族二胺配体结合而形成的。在氩气气氛中研究了化合物和的热行为。
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