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利用紫外光活化的GA-TiO-Cd复合材料降解橙黄G、酸性蓝161和亮绿染料

Degradation of Orange G, Acid Blue 161, and Brillant Green Dyes Using UV Light-Activated GA-TiO-Cd Composite.

作者信息

Tekin Derya, Birhan Derya, Tekin Taner, Kiziltas Hakan

机构信息

Department of Metallurgy and Materials Engineering Ataturk University Erzurum 25240 Turkey.

Department of Chemical Engineering Ataturk University Erzurum 25240 Turkey.

出版信息

Glob Chall. 2024 Apr 14;8(5):2300271. doi: 10.1002/gch2.202300271. eCollection 2024 May.

Abstract

In this study, photocatalysts with high photocatalytic activity performance are synthesized by synthesizing graphene aerogel-supported, cadmium-doped TiO composites by hydrothermal method for the effective degradation of organic dyes in wastewater. Here, GA-TiO-Cd is investigated as a photocatalyst for the degradation of toxic dyes named Orange G, Acid Blue 161, and Brilliant Green in the UV part of the light spectrum. As a result of the experiments, it is observed that the effective decomposition of organic dyes is due to graphene aerogel (GA) and cadmium-doped TiO nanoparticles. The results show that for 20 ppm solutions of Orange G, Acid Blue 161, and Brilliant Green, dyes are removed at approximately 81.075%, 84.15%, and 95.18% in 120 min. The morphology and elemental analysis of the synthesized composites are determined using SEM-EDS, crystal structure analysis by XRD, chemical bond analysis by FTIR, optical properties by UV-Vis-NIR spectrophotometry, and thermal resistance by TGA analysis.

摘要

在本研究中,通过水热法合成石墨烯气凝胶负载的镉掺杂TiO复合材料,制备出具有高光催化活性的光催化剂,用于有效降解废水中的有机染料。在此,研究了GA-TiO-Cd作为光催化剂在紫外光谱部分对名为橙黄G、酸性蓝161和亮绿的有毒染料的降解情况。实验结果表明,有机染料的有效分解归因于石墨烯气凝胶(GA)和镉掺杂的TiO纳米颗粒。结果显示,对于20 ppm的橙黄G、酸性蓝161和亮绿溶液,在120分钟内染料的去除率分别约为81.075%、84.15%和95.18%。使用扫描电子显微镜-能谱仪(SEM-EDS)确定合成复合材料的形态和元素分析,通过X射线衍射(XRD)进行晶体结构分析,利用傅里叶变换红外光谱(FTIR)进行化学键分析,通过紫外-可见-近红外分光光度法(UV-Vis-NIR)测定光学性质,并通过热重分析(TGA)分析热稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/393a/11090212/52de690b8823/GCH2-8-2300271-g006.jpg

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