Edebali Özge, Krupčíková Simona, Goellner Anna, Vrana Branislav, Muz Melis, Melymuk Lisa
RECETOX, Masaryk University, Faculty of Science, Kotlářská 2, 611 37 Brno, Czechia.
UFZ Helmholtz Centre for Environmental Research, Department of Effect Directed Analysis, Permoserstr. 15, 04318 Leipzig, Germany.
Environ Sci Technol Lett. 2024 Apr 10;11(5):397-409. doi: 10.1021/acs.estlett.4c00032. eCollection 2024 May 14.
This review examines the environmental occurrence and fate of aromatic amines (AAs), a group of environmental contaminants with possible carcinogenic and mutagenic effects. AAs are known to be partially responsible for the genotoxic traits of industrial wastewater (WW), and AA antioxidants are acutely toxic to some aquatic organisms. Still, there are gaps in the available data on sources, occurrence, transport, and fate in domestic WW and indoor environments, which complicate the prevention of adverse effects in aquatic ecosystems. We review key domestic sources of these compounds, including cigarette smoke and grilled protein-rich foods, and their presence indoors and in aquatic matrices. This provides a basis to evaluate the importance of nonindustrial sources to the overall environmental burden of AAs. Appropriate sampling techniques for AAs are described, including copper-phthalocyanine trisulfonate materials, XAD resins in solid-phase extraction, and solid-phase microextraction methods, which can offer insights into AA sources, transport, and fate. Further discussion is provided on potential progress in the research of AAs and their behavior in an aim to support the development of a more comprehensive understanding of their effects and potential environmental risks.
本综述探讨了芳香胺(AAs)在环境中的存在情况及其归宿,芳香胺是一类具有潜在致癌和致突变作用的环境污染物。已知芳香胺是工业废水(WW)遗传毒性特征的部分成因,且芳香胺抗氧化剂对某些水生生物具有急性毒性。然而,关于生活污水和室内环境中这些化合物的来源、存在情况、迁移和归宿的现有数据仍存在空白,这使得预防水生生态系统中的不利影响变得复杂。我们综述了这些化合物在生活中的主要来源,包括香烟烟雾和烤制的富含蛋白质的食物,以及它们在室内和水生基质中的存在情况。这为评估非工业来源对芳香胺整体环境负担的重要性提供了依据。文中描述了针对芳香胺的适当采样技术,包括铜酞菁三磺酸盐材料、固相萃取中的XAD树脂以及固相微萃取方法,这些方法有助于深入了解芳香胺的来源、迁移和归宿。本文还进一步讨论了芳香胺研究及其行为方面的潜在进展,旨在支持对其影响和潜在环境风险形成更全面的认识。