Review of recent progress in the development of electrolytes for Cd/Pb-based quantum dot-sensitized solar cells: performance and stability.

Quantum dot-sensitized solar cells (QDSSCs) represent an exciting advancement in third-generation photovoltaic solar cells owing to their ability to generate multiple electron-hole pairs per photon, high stability under light and moisture exposure, and flexibility in size and composition tuning. Although these cells have achieved power conversion efficiencies exceeding 15%, there remains a challenge in enhancing both their efficiency and stability for practical large-scale applications. Therefore, in this review, we aimed to investigate recent progress in improving the long-term stability, analyzing the impact of advanced quantum dot properties on charge-transport optimization, and assessing the role of interface engineering in reducing recombination losses to maximize QDSSC performance and stability. Additionally, this review delves into key elements such as the electrolyte composition, ionic conductivity, and compatibility with counter electrodes and photoanodes to understand their influence on power conversion efficiencies and stability. Finally, potential directions for advancing QDSC development in future are discussed to provide insights into the obstacles and opportunities for achieving high-efficiency QDSSCs.