Inoue Miku, Yamauchi Akio, Parmar Bhavesh, Orihashi Kana, Singh Manpreet, Asada Mizue, Nakamura Toshikazu, Yanai Nobuhiro
Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan.
Institute for Molecular Science, Nishigonaka 38, Myodaiji, Okazaki 444-8585, Japan.
Chem Commun (Camb). 2024 Jun 11;60(48):6130-6133. doi: 10.1039/d4cc01564a.
Metal-organic frameworks (MOFs) integrated with molecular qubits are promising for quantum sensing. In this study, a new UiO-type MOF with a 5,12-diazatetracene (DAT)-containing ligand is synthesized, and the radicals generated in the MOF exhibit high stability and a relatively long coherence time () responsive to the introduction of various guest molecules.
与分子量子比特集成的金属有机框架（MOF）在量子传感方面具有广阔前景。在本研究中，合成了一种含有5,12 - 二氮杂并四苯（DAT）配体的新型UiO型MOF，并且该MOF中产生的自由基对各种客体分子的引入表现出高稳定性和相对较长的相干时间（）。
