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推进可持续废水管理:营养回收产品及其应用的综合评述。

Advancing sustainable wastewater management: A comprehensive review of nutrient recovery products and their applications.

机构信息

Faculty of Civil and Environmental Engineering, Gdansk University of Technology, Narutowicza 11/12, Gdańsk, Poland.

Faculty of Civil and Environmental Engineering, Gdansk University of Technology, Narutowicza 11/12, Gdańsk, Poland.

出版信息

Sci Total Environ. 2024 Aug 10;937:173446. doi: 10.1016/j.scitotenv.2024.173446. Epub 2024 May 23.

Abstract

Wastewater serves as a vital resource for sustainable fertilizer production, particularly in the recovery of nitrogen (N) and phosphorus (P). This comprehensive study explores the recovery chain, from technology to final product reuse. Biomass growth is the most cost-effective method, valorizing up to 95 % of nutrients, although facing safety concerns. Various techniques enable the recovery of 100 % P and up to 99 % N, but challenges arise during the final product crystallization due to the high solubility of ammonium salts. Among these techniques, chemical precipitation and ammonia stripping/ absorption have achieved full commercialization, with estimated recovery costs of 6.0-10.0 EUR kgP and 4.4-4.8 £ kgN, respectively. Multiple technologies integrating biomass thermo-chemical processing and P and/or N have also reached technology readiness level TRL = 9. However, due to maturing regulatory of waste-derived products, not all of their products are commercially available. The non-homogenous nature of wastewater introduces impurities into nutrient recovery products. While calcium and iron impurities may impact product bioavailability, some full-scale P recovery technologies deliver products containing this admixture. Recovered mineral nutrient forms have shown up to 60 % higher yield biomass growth compared to synthetic fertilizers. Life cycle assessment studies confirm the positive environmental outcomes of nutrient recycling from wastewater to agricultural applications. Integration of novel technologies may increase wastewater treatment costs by a few percent, but this can be offset through renewable energy utilization and the sale of recovered products. Moreover, simultaneous nutrient recovery and energy production via bio-electrochemical processes contributes to carbon neutrality achieving. Interdisciplinary cooperation is essential to offset both energy and chemicals inputs, increase their cos-efficiency and optimize technologies and understand the nutrient release patterns of wastewater-derived products on various crops. Addressing non-technological factors, such as legal and financial support, infrastructure redesign, and market-readiness, is crucial for successfully implementation and securing the global food production.

摘要

污水是可持续肥料生产的重要资源,尤其在氮(N)和磷(P)的回收方面。本综合研究探讨了从技术到最终产品再利用的回收链。生物质增长是最具成本效益的方法,可将高达 95%的养分加以利用,尽管存在安全问题。各种技术可实现 100%P 和高达 99%N 的回收,但在最终产品结晶过程中,由于铵盐的高溶解度,会出现挑战。在这些技术中,化学沉淀和氨汽提/吸收已实现完全商业化,磷的回收成本估计为 6.0-10.0 欧元/千克 P,氮的回收成本为 4.4-4.8 英镑/千克 N。同时集成生物质热化学处理以及 P 和/或 N 的多种技术也达到了技术就绪水平 TRL=9。然而,由于废物衍生产品的监管法规不断成熟,并非所有产品都可进行商业应用。污水的非均质性会将杂质引入养分回收产品中。尽管钙和铁杂质可能会影响产品的生物有效性,但一些全规模 P 回收技术提供的产品中就含有这种混合物。与合成肥料相比,回收的矿物养分形式可使生物质生长的产量提高高达 60%。生命周期评估研究证实了从污水中回收养分并应用于农业的积极环境效益。新型技术的整合可能会使污水处理成本增加几个百分点,但可以通过利用可再生能源和销售回收产品来抵消这部分成本。此外,通过生物电化学过程同时进行养分回收和能源生产有助于实现碳中和。跨学科合作对于抵消能源和化学品投入、提高其共同效率、优化技术以及了解污水衍生产品在各种作物上的养分释放模式至关重要。解决非技术因素,如法律和财政支持、基础设施重新设计以及市场准备度,对于成功实施和确保全球粮食生产至关重要。

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