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从可行原料生产乙炔:近期有前景的方法。

Production of Acetylene from Viable Feedstock: Promising Recent Approaches.

作者信息

Gyrdymova Yulia V, Lebedev Andrei N, Du Yan-Jun, Rodygin Konstantin S

机构信息

Saint Petersburg State University, St. Petersburg, 199034, Russia.

Jiangsu Key Laboratory of Low Carbon and Sustainable Geotechnical Engineering, Institute of Geotechnical Engineering, Southeast University, Nanjing, 211189, China.

出版信息

Chempluschem. 2024 Nov;89(11):e202400247. doi: 10.1002/cplu.202400247. Epub 2024 Jul 9.

Abstract

The potential of acetylene is extremely high both in chemical industry and synthetic applications due to unsaturated nature and the smallest active C≡C unit. The production of many essential necessities is originated from acetylene; however, the formation of acetylene molecule requires a lot of energy. Currently, the access to acetylene is based on coal processing, methane reforming and calcium carbide hydrolysis. Recently, extensive research has been done to decrease the cost of acetylene. In this review, the routes to acetylene were highlighted, considering the energy consumption in kW ⋅ h/t of the product to evaluate the best approach. Since energy prices depend on various regions, the cost of the product is complicated. The manufacturing of acetylene is usually accompanied by formation of by-products, which may be valuable or not. The review should help to identify current status and not overlook promising approaches.

摘要

由于乙炔的不饱和性质以及最小的活性C≡C单元,其在化学工业和合成应用中的潜力极高。许多必需品的生产都源自乙炔;然而,乙炔分子的形成需要大量能量。目前,乙炔的获取基于煤炭加工、甲烷重整和电石水解。最近,人们进行了广泛的研究以降低乙炔的成本。在这篇综述中,突出了乙炔的制备路线,并考虑了每生产一吨产品的能耗(单位:kW⋅h/t)来评估最佳方法。由于能源价格因地区而异,产品成本较为复杂。乙炔的制造通常伴随着副产物的形成,这些副产物可能有价值,也可能没有价值。这篇综述应有助于认清当前状况,且不会忽视有前景的方法。

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