Mu Chaoqun, Jian Shijin, Zhang Mingming
School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology, Xi'an, Shaanxi, 710055, P. R. China.
State Key Laboratory for Mechanical Behavior of Materials, Shaanxi International Research Center for Soft Matter, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049, P. R. China.
Chemistry. 2024 Aug 1;30(43):e202401264. doi: 10.1002/chem.202401264. Epub 2024 Jul 15.
Metal-organic frameworks (MOFs) and metal-organic cages (MOCs) have garnered significant attention as promising photocatalysts due to their tunable chemical structures and integrated multifunctionality. To increase the photocatalytic efficiency, strategies like ligand functionalization, introducing additional catalytic sites, and doping or encapsulating photosensitizers have been explored for both MOFs and MOCs. This concept review focuses on recent advancements in utilizing MOFs and MOCs for photocatalytic hydrogen production, highlighting their unique characteristics and introducing their respective mechanisms in this field. Moreover, it outlines the current challenges and prospects faced by MOFs and MOCs, offering an outlook on their future in this domain.
金属有机框架（MOFs）和金属有机笼（MOCs）因其可调节的化学结构和集成的多功能性，作为有前景的光催化剂已引起了广泛关注。为了提高光催化效率，人们已经探索了诸如配体功能化、引入额外催化位点以及掺杂或封装光敏剂等策略用于MOFs和MOCs。这篇概念综述聚焦于利用MOFs和MOCs进行光催化产氢的最新进展，突出它们的独特特性，并介绍它们在该领域各自的机制。此外，它概述了MOFs和MOCs目前面临的挑战和前景，展望了它们在该领域的未来。
