Pilgrim Ben S, Champness Neil R
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, United Kingdom.
Chempluschem. 2020 Aug;85(8):1842-1856. doi: 10.1002/cplu.202000408.
The fields of metal-organic cages (MOCs) and metal-organic frameworks (MOFs) are both highly topical and continue to develop at a rapid pace. Despite clear synergies between the two fields, overlap is rarely observed. This article discusses the peculiarities and similarities of MOCs and MOFs in terms of synthetic strategies and approaches to system characterisation. The stability of both classes of material is compared, particularly in relation to their applications in guest storage and catalysis. Lastly, suggestions are made for opportunities for each field to learn and develop in partnership with the other.
金属有机笼（MOCs）和金属有机框架（MOFs）领域都是当前备受关注的热门领域，并且仍在快速发展。尽管这两个领域之间存在明显的协同效应，但很少观察到重叠现象。本文从合成策略和系统表征方法的角度讨论了MOCs和MOFs的特点与相似之处。比较了这两类材料的稳定性，特别是在客体存储和催化应用方面的稳定性。最后，针对每个领域相互学习与合作发展的机会提出了建议。
