Panda Sourav Kumar, De Antara, Banerjee Supratim
The Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, Nadia, India.
Photochem Photobiol. 2024 Jul-Aug;100(4):796-829. doi: 10.1111/php.13956. Epub 2024 Jun 4.
In recent years, organic materials with room-temperature phosphorescence (RTP) features have gained significant attention due to their wide applications in the fields of bioimaging, light-harvesting materials, encryption technology, etc. Although several examples of organic RTP materials in the crystalline state and polymer-based systems have been reported in the last decade or so, achieving organic RTP in the solution phase, particularly in the aqueous phase has remained a challenging task. Herein in this review, we summarize the progress in this direction by highlighting design strategies based on supramolecular scaffolding and host-guest complexation and the applications of such aqueous organic RTP materials in bioimaging, sensing, etc.
近年来,具有室温磷光(RTP)特性的有机材料因其在生物成像、光捕获材料、加密技术等领域的广泛应用而备受关注。尽管在过去十年左右已经报道了一些处于结晶态和基于聚合物体系的有机RTP材料的例子,但在溶液相中,特别是在水相中实现有机RTP仍然是一项具有挑战性的任务。在本综述中,我们通过强调基于超分子支架和主客体络合的设计策略以及此类水性有机RTP材料在生物成像、传感等方面的应用,总结了这一方向的进展。