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一种新型碳纤维和石墨改性泡沫混凝土的制备:基于X射线计算机断层扫描的力学、电磁和微观结构特性

Preparation of a novel foamed concrete modified with carbon fiber and graphite: Mechanical, electro-magnetic and microstructural characteristics based on X-CT.

作者信息

Tu Qin-Chuan, Xia Qing-Hui, Lu Yao, Bai Ying-Hua

机构信息

School of Civil Engineering, Architecture and Environment, Hubei University of Technology, Wuhan, 430068, China.

Key Laboratory of Intelligent Health Perception and Ecological Restoration of Rivers and Lakes, Ministry of Education, Hubei University of Technology, Wuhan, 430068, China.

出版信息

Heliyon. 2024 May 23;10(11):e31665. doi: 10.1016/j.heliyon.2024.e31665. eCollection 2024 Jun 15.

Abstract

In this paper, foam concrete is modified using graphite and carbon fiber as absorbents. The mechanical properties are analyzed in conjunction with hydration products, pore size distribution based on XCT test. Additionally, the resistivity, complex permittivity and complex permeability are tested. The results demonstrate that carbon fiber enhances the proportion of pores with diameters less than 200 μm in foam concrete, thereby significantly enhancing its flexural strength. Furthermore, incorporating graphite helps offset the initial retardation of sulfoaluminate cement hydration induced by carbon fibers, leading to an increase in the average pore size and a reduction in compressive strength. The incorporation of carbon fibers at a concentration of 0.6 wt% achieves the percolation threshold, akin to scenarios with singular fiber incorporation. Exceeding 2 wt% graphite content results in negligible influence on the conductivity. The synergistic integration of graphite and carbon fibers significantly improves the electromagnetic wave absorption performance of the composite. At a thickness of 6 mm, the material exhibits an effective bandwidth where the reflection loss is less than -10 dB, extending up to 2.5 GHz, which constitutes 52.08 % of the tested frequency spectrum.

摘要

本文以石墨和碳纤维为吸收剂对泡沫混凝土进行改性。结合水化产物分析其力学性能,并基于XCT试验分析孔径分布。此外,还测试了电阻率、复介电常数和复磁导率。结果表明,碳纤维提高了泡沫混凝土中直径小于200μm的孔隙比例,从而显著提高了其抗弯强度。此外,加入石墨有助于抵消碳纤维引起的硫铝酸盐水泥水化初期的延迟,导致平均孔径增大和抗压强度降低。以0.6wt%的浓度加入碳纤维达到了渗流阈值,类似于单纤维加入的情况。石墨含量超过2wt%对电导率的影响可忽略不计。石墨和碳纤维的协同集成显著提高了复合材料的电磁波吸收性能。在厚度为6mm时,该材料表现出有效带宽,其中反射损耗小于-10dB,扩展至2.5GHz,占测试频谱的52.08%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e93/11153095/282b5a0c788b/gr1.jpg

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